Structural characteristics and dielectric properties of neodymium doped barium titanate

• Published in: Journal of materials science. Materials in electronics 2011-02, Vol.22 (2), p.167-173
• Main Authors: Rejab, Nik Akmar, Sreekantan, Srimala, Abd Razak, Khairunisak, Ahmad, Zainal Arifin
• Format: Article
• Language: English
• Subjects: Applied sciences; Barium titanates; Characterization and Evaluation of Materials; Chemistry and Materials Science; Circuit properties; Concentration (composition); Condensed matter: electronic structure, electrical, magnetic, and optical properties; Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder; Cross-disciplinary physics: materials science; rheology; Dielectric loss; Dielectric properties of solids and liquids; Dielectrics, piezoelectrics, and ferroelectrics and their properties; Doping; Electric, optical and optoelectronic circuits; Electronic circuits; Electronics; Exact sciences and technology; Materials Science; Materials synthesis; materials processing; Neodymium; Optical and Electronic Materials; Oscillators, resonators, synthetizers; Permittivity (dielectric function); Phase diagrams and microstructures developed by solidification and solid-solid phase transformations; Physics; Sol gel process; X-band
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-010-0108-9

Neodymium (Nd) doped barium titanate powder (Ba (1− x ) Nd x TiO 3 ) with x value varying from 0, 0.01, 0.03, 0.05, 0.07, 0.10 and 0.13 was prepared using the sol gel method. The powder samples were calcined at 700 °C and tetragonal phase appeared in the powders before they were sintered at 1250 °C for 3 h. The undoped samples have a polycrystalline tetragonal structure, but Nd doping into the BaTiO 3 caused phase transformation from tetragonal to cubic. The smaller grains (0.35 μm) produced with the addition of Nd is associated to the inhibition of grain growth of samples. The powders for each composition were pressed into pellets and tested as dielectric resonator antenna (DRA). It was found that on the actual antenna circuit, each sample showed a resonance frequency at X-band application and a dielectric constant value in the range of 51.25–56.89 and tangent loss was 0.039–0.045, depending on the concentration of the Nd at room temperature.