Optimization of PVC- PAN-based polymer electrolytes

The hybrid plasticized polymer electrolyte composed of the blend of poly(vinyl chloride) (PVC) and poly(acrylonitrile) (PAN) as host polymer, propylene carbonate as plasticizer, and LiClO₄ as a salt was studied. An attempt was made to optimize the polymer blend ratio. XRD, Fourier transform infrared...

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Bibliographic Details
Published in:Journal of applied polymer science 2009-08, Vol.113 (3), p.1651-1656
Main Authors: Rajendran, Somasundaram, Babu, Ravishanker, Sivakumar, Periyasami
Format: Article
Language:English
Subjects:
Applied sciences
Chlorides
Electrical, magnetic and optical properties
Electrolytes
Exact sciences and technology
FTIR and impedance studies
Organic polymers
Physicochemistry of polymers
Plasticizers
Polymer blends
Polyvinyl chlorides
Properties and characterization
Propylene
PVC/PAN polymer blend electrolytes
Reproduction
Resistivity
Temperature dependence
XRD
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Summary:The hybrid plasticized polymer electrolyte composed of the blend of poly(vinyl chloride) (PVC) and poly(acrylonitrile) (PAN) as host polymer, propylene carbonate as plasticizer, and LiClO₄ as a salt was studied. An attempt was made to optimize the polymer blend ratio. XRD, Fourier transform infrared, and DSC studies confirm the formation of polymer-salt complex and miscibility of the PVC and PAN. The electrical conductivity and temperature dependence of ionic conductivity of polymer films are also studied and reported here.
ISSN:0021-8995
1097-4628
1097-4628
DOI:10.1002/app.30174