From microstructure to the development of water and major reaction sites inside the catalyst layer of the cathode of a proton exchange membrane fuel cell

• Published in: Journal of power sources 2011-09, Vol.196 (18), p.7411-7419
• Main Authors: Lee, Ming-San, Chen, T.H., Lee, W.S., Lin, B.S., Lau, B.Y., Tsai, P.F., Wang, G.C.
• Format: Article
• Language: English
• Subjects: Applied sciences; Catalysts; Cathode; Cathodes; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Major reaction sites; Microstructure; Proposals; Proton exchange membrane fuel cell; Proton exchange membrane fuel cells; Rest; Steady state; Transient responses; Water surface
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2011.04.022

► There is a water “surface” existing in the catalyst layer (CL). ► Major reactions can only occur above and within a limited height of this surface. ► Microstructure (MS) on the surface of CL can significantly improve its performance. ► The increase in interface area from MS is proportional to the performance increase. ► A performance “jump” appears in all MEAs with MS in the periodic linear sweep test. Microstructures of various sizes and shapes are fabricated on the surface of the catalyst layer (CL) of the cathode of a PEMFC, adjacent to the micro porous layer (MPL). Three major experimental results are: (1) performance is improved by up to 60% and the percentage of the increase is the same as that of the increase in interface area of CL and MPL; (2) the cell suffers no significant performance loss when Pt loading of the cathode is reduced from 1 to 0.25 mg cm −2 and; (3) transient responses in periodical linear sweep tests show an obvious performance “jump” for all the cathodes with microstructures when approaching steady state, but none for others. Based on observations, a proposal related to the development of water and, consequently, the major reaction sites in the CL is made: there is a general water “surface” inside the CL. Major electrochemical reactions occur above (on the MPL side) of this surface and within a limited height. The surface will “move” from the membrane toward the MPL as more water is produced. The vapor generation rate (current load) relative to the removal rate of the rest of the cell components will determine the steady state position of this water surface.