N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)

Reactions of N-heterocyclic carbene stabilized dichlorosilylene IPr·SiCl2 (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with (η5-C5H5)V(CO)4, (η5-C5H5)Co(CO)2, and Fe2(CO)9 afford dichlorosilylene complexes IPr·SiCl2·V(CO)3(η5-C5H5) (2), IPr·SiCl2·Co(CO)(η5-C5H5) (3), and IPr·SiCl2·Fe...

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Published in:Inorganic chemistry 2011-09, Vol.50 (17), p.8502-8508
Main Authors: Ghadwal, Rajendra S, Azhakar, Ramachandran, Pröpper, Kevin, Holstein, Julian J, Dittrich, Birger, Roesky, Herbert W
Format: Article
Language:English
Subjects:
Crystallography, X-Ray
Heterocyclic Compounds - chemistry
Methane - analogs & derivatives
Methane - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Silicon Compounds - chemistry
Stereoisomerism
Transition Elements - chemistry
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cited_by cdi_FETCH-LOGICAL-a415t-3cf81068d5e419012e9ffb5511689d064247cff706ae8268062e25a70de4403e3
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container_issue 17
container_start_page 8502
container_title Inorganic chemistry
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creator Ghadwal, Rajendra S
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description Reactions of N-heterocyclic carbene stabilized dichlorosilylene IPr·SiCl2 (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with (η5-C5H5)V(CO)4, (η5-C5H5)Co(CO)2, and Fe2(CO)9 afford dichlorosilylene complexes IPr·SiCl2·V(CO)3(η5-C5H5) (2), IPr·SiCl2·Co(CO)(η5-C5H5) (3), and IPr·SiCl2·Fe(CO)4 (4), respectively. Complexes 2–4 are stable under an inert atmosphere, are soluble in common organic solvents, and have been characterized by elemental analysis and multinuclear (1H, 13C, and 29Si) NMR spectroscopy. Molecular structures of 2–4 have been determined by single crystal X-ray crystallographic studies and refined with nonspherical scattering factors.
doi_str_mv 10.1021/ic201096c
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Crystallography, X-Ray
Heterocyclic Compounds - chemistry
Methane - analogs & derivatives
Methane - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Silicon Compounds - chemistry
Stereoisomerism
Transition Elements - chemistry
title N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)
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