Synthesis and properties of copolymer of 3-thienylmethyl disulfide and benzyl disulfide for cathode material in lithium batteries

• Published in: Journal of applied polymer science 2010-04, Vol.116 (2), p.727-735
• Main Authors: Weng, Guoming, Su, Yuzhi, Liu, Zhaoqing, Wu, Zhaoyi, Chen, Shuang, Zhang, Jianhua, Xu, Changwei
• Format: Article
• Language: English
• Subjects: Applied sciences; Carbon; cathode material; Cathodes; conducting polymers; copolymerization; Copolymers; Direct energy conversion and energy accumulation; Disulfides; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Electrodes; Exact sciences and technology; Lithium; Lithium batteries; lithium battery; Physicochemistry of polymers; Polymerization; Polymers and radiations; redox polymers; Reproduction
• ISSN: 0021-8995; 1097-4628; 1097-4628
• DOI: 10.1002/app.31383

The copolymerization of 3-thienylmethyl disulfide and benzyl disulfide has been investigated. Two monomers were synthesized in a novel facile way. Copolymer of them, especially poly (3-thienylmethyl disulfide-co-benzyl disulfide), ratio 1 : 4, namely, TcB₁:₄, was easily electrocopolymerized to form a stable and higher conductive structure at a lower potential on Pt, Au, or glass carbon electrode. TcB₁:₄ and TcB₄:₁, especially the former, exhibit better conductivities than those of pure poly 3-thienylmethyl disulfide and poly benzyl disulfide. The copolymer has larger areas than that of monopolymer by cyclic voltammogram measurement. The copolymer shows a capability of supplying more power and energy than monopolymer itself. Copolymers could be used as cathode materials for lithium secondary batteries because their functional groups could not be destroyed before 80°C. In scanning electron micrography, the copolymers show larger compacter structure. The results of the copolymer systems show that they are potentials as cathode materials for lithium batteries.