Aqueous chloramine diffusion into elastomers

• Published in: Journal of applied polymer science 2010-09, Vol.117 (5), p.2597-2611
• Main Authors: Nagisetty, Raja M., Rockaway, Thomas D., Willing, Gerold A.
• Format: Article
• Language: English
• Subjects: Ageing; Applied sciences; Approximation; aqueous chloramine; Butadiene; Diffusion; Diffusion coefficient; drinking water distribution system; elastomer; Elastomers; Exact sciences and technology; Failure; Intakes; Mathematical analysis; Natural rubber; Physical properties; Polymer industry, paints, wood; Properties and testing; Reproduction; Styrenes; Swelling; Technology of polymers
• ISSN: 0021-8995; 1097-4628; 1097-4628
• DOI: 10.1002/app.30970

Aqueous chloramine diffusion into styrene butadiene rubber (SBR) and natural rubber was analyzed using approximate analytical and numerical solutions of Fick's second law of diffusion to develop long‐term mass intake prediction curves. Diffusion coefficients were calculated for 1 mg/L chloramine concentration at three temperatures (23, 45, and 70°C) and also for 23°C at three chloramine concentrations (1, 30, and 60 mg/L). The reasonableness of using increased temperature and/or chloramine concentration to accelerate the diffusion process to obtain long‐term information was discussed. For 1 mg/L chloramine concentration, the activation energy for the diffusion of chloramines into SBR and natural rubber were computed to be 51.13 and 77.29 kJ/mol, respectively. Also, concentration profiles were developed to understand the extent of penetration through the elastomer thickness over time and temperature. Considering the reports of elastomeric compound failure in chloramine disinfectant water distribution systems because of swelling, this study will be helpful in understanding the performance of the elastomeric compounds in the system. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010