Hydrogen-rich gas production from oxygen pressurized gasification of biomass using a Fe–Cr Water Gas Shift catalyst

• Published in: International journal of hydrogen energy 2010, Vol.35 (1), p.37-45
• Main Authors: Maroño, M., Sánchez, J.M., Ruiz, E.
• Format: Article
• Language: English
• Subjects: Alternative fuels. Production and utilization; Applied sciences; Biomass; Carbon monoxide; Catalysts; Drying; Energy; Exact sciences and technology; Fe–Cr catalyst; Fuels; Gasification; H 2 production; Hydrogen; Iron; Membrane reactor; Outlets; Oxygen gasification; Reactors; WGS
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2009.10.078

In this paper the catalytic activity of a Fe–Cr WGS catalyst is evaluated in terms of CO conversion and H 2 production. The experimental study has been carried out under realistic conditions typical of oxygen pressurized gasification of biomass. The influence of temperature, excess steam, feed gas composition and space velocity on the activity and selectivity of the catalyst for the WGS reaction is investigated. The experimental work was carried out in a micro reactor testing unit using synthetic gas feed mixtures. Despite the high CO content in the feed gas (44–60% dry basis) the catalyst has shown very good performance at intermediate temperatures 350–450 °C, providing hydrogen content increases in the exit gas in the range of 10–17% (dry basis) and CO concentration at the reactor outlet lower than 3% v/v. Best performance operating conditions and the suitability of the catalyst to be incorporated in a palladium membrane reactor is discussed in this article.