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Use of β-cyclodextrins to control the structure of water-soluble copolymers with hydrophobic parts
In this article, we present the synthesis and characterization of water-soluble polymers with hydrophobic moieties. The polymers were synthesized in aqueous solutions utilizing β-cyclodextrins as solubility enhancers to bring the hydrophobic monomers into solution. Polymers were made with different...
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| Published in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2009-12, Vol.47 (23), p.6619-6629 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c4294-2100ba71e29a14911f727f4cd683397ad4a7edceb8cad474e8e20df3002f17573 |
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| cites | cdi_FETCH-LOGICAL-c4294-2100ba71e29a14911f727f4cd683397ad4a7edceb8cad474e8e20df3002f17573 |
| container_end_page | 6629 |
| container_issue | 23 |
| container_start_page | 6619 |
| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 47 |
| creator | Nielsen, A.L Andersen, M.B.O Bugge, T.V Nielsen, C.F Nielsen, T.B Wimmer, R Yu, D Larsen, K.L |
| description | In this article, we present the synthesis and characterization of water-soluble polymers with hydrophobic moieties. The polymers were synthesized in aqueous solutions utilizing β-cyclodextrins as solubility enhancers to bring the hydrophobic monomers into solution. Polymers were made with different spacing between polymer backbone and phenyl moiety by using styrene, allylbenzene, and 4-phenyl-1-butene as hydrophobic moieties, respectively. The effect of the presence of CDs during synthesis as well as this difference in spacing was investigated by rebinding free β-CDs to the polymers. The interactions between polymers and CDs were studied by ITC and this revealed some differences between the polymers. Polymers made in the presence of CDs showed a markedly stronger binding to free CDs. The same was observed with polymers with a longer spacing between backbone and phenyl moiety. |
| doi_str_mv | 10.1002/pola.23704 |
| format | article |
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The polymers were synthesized in aqueous solutions utilizing β-cyclodextrins as solubility enhancers to bring the hydrophobic monomers into solution. Polymers were made with different spacing between polymer backbone and phenyl moiety by using styrene, allylbenzene, and 4-phenyl-1-butene as hydrophobic moieties, respectively. The effect of the presence of CDs during synthesis as well as this difference in spacing was investigated by rebinding free β-CDs to the polymers. The interactions between polymers and CDs were studied by ITC and this revealed some differences between the polymers. Polymers made in the presence of CDs showed a markedly stronger binding to free CDs. 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Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>In this article, we present the synthesis and characterization of water-soluble polymers with hydrophobic moieties. The polymers were synthesized in aqueous solutions utilizing β-cyclodextrins as solubility enhancers to bring the hydrophobic monomers into solution. Polymers were made with different spacing between polymer backbone and phenyl moiety by using styrene, allylbenzene, and 4-phenyl-1-butene as hydrophobic moieties, respectively. The effect of the presence of CDs during synthesis as well as this difference in spacing was investigated by rebinding free β-CDs to the polymers. The interactions between polymers and CDs were studied by ITC and this revealed some differences between the polymers. Polymers made in the presence of CDs showed a markedly stronger binding to free CDs. The same was observed with polymers with a longer spacing between backbone and phenyl moiety.</description><subject>Applied sciences</subject><subject>Backbone</subject><subject>Cadmium sulfides</subject><subject>calorimetry</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>cyclodextrins</subject><subject>Exact sciences and technology</subject><subject>host-guest systems</subject><subject>Monomers</subject><subject>Organic polymers</subject><subject>Phenyls</subject><subject>Physicochemistry of polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>radical polymerization</subject><subject>Reproduction</subject><subject>Solubility</subject><subject>supramolecular structures</subject><subject>Synthesis</subject><issn>0887-624X</issn><issn>1099-0518</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkM1u1DAUhS0EEkNhwwvgDUJCSvFf4nhZFehUGrWVygh2lse5ZgKecbAdTfNaPAjPhNuULunKV_J3zr3nIPSakmNKCPswBG-OGZdEPEELSpSqSE3bp2hB2lZWDRPfnqMXKf0gpPzV7QLZdQIcHP7zu7KT9aGDmxz7fcI5YBv2OQaP8xZwynG0eYx38MFkiFUKftx4KFjZOu0gJnzo8xZvpy6GYRs2vcWDiTm9RM-c8Qle3b9HaP3505fTZbW6PDs_PVlVVjAlKlYSbIykwJShQlHqJJNO2K5pOVfSdMJI6CxsWltmKaAFRjrHS25HZS35EXo3-w4x_BohZb3rkwXvzR7CmLQitJG8JuxRslVNKZEJVcj3M2ljSCmC00PsdyZOmhJ9W7m-rVzfVV7gt_e2JlnjXTR726cHBWOUl0N54ejMHXoP038c9dXl6uSfdzVr-pTh5kFj4k9dQslaf70402J5vfzYFItV4d_MvDNBm--x3LG-ZoRyQiUhtaT8Lwflqs8</recordid><startdate>20091201</startdate><enddate>20091201</enddate><creator>Nielsen, A.L</creator><creator>Andersen, M.B.O</creator><creator>Bugge, T.V</creator><creator>Nielsen, C.F</creator><creator>Nielsen, T.B</creator><creator>Wimmer, R</creator><creator>Yu, D</creator><creator>Larsen, K.L</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20091201</creationdate><title>Use of β-cyclodextrins to control the structure of water-soluble copolymers with hydrophobic parts</title><author>Nielsen, A.L ; Andersen, M.B.O ; Bugge, T.V ; Nielsen, C.F ; Nielsen, T.B ; Wimmer, R ; Yu, D ; Larsen, K.L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4294-2100ba71e29a14911f727f4cd683397ad4a7edceb8cad474e8e20df3002f17573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Backbone</topic><topic>Cadmium sulfides</topic><topic>calorimetry</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>cyclodextrins</topic><topic>Exact sciences and technology</topic><topic>host-guest systems</topic><topic>Monomers</topic><topic>Organic polymers</topic><topic>Phenyls</topic><topic>Physicochemistry of polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>radical polymerization</topic><topic>Reproduction</topic><topic>Solubility</topic><topic>supramolecular structures</topic><topic>Synthesis</topic><toplevel>online_resources</toplevel><creatorcontrib>Nielsen, A.L</creatorcontrib><creatorcontrib>Andersen, M.B.O</creatorcontrib><creatorcontrib>Bugge, T.V</creatorcontrib><creatorcontrib>Nielsen, C.F</creatorcontrib><creatorcontrib>Nielsen, T.B</creatorcontrib><creatorcontrib>Wimmer, R</creatorcontrib><creatorcontrib>Yu, D</creatorcontrib><creatorcontrib>Larsen, K.L</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nielsen, A.L</au><au>Andersen, M.B.O</au><au>Bugge, T.V</au><au>Nielsen, C.F</au><au>Nielsen, T.B</au><au>Wimmer, R</au><au>Yu, D</au><au>Larsen, K.L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Use of β-cyclodextrins to control the structure of water-soluble copolymers with hydrophobic parts</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>2009-12-01</date><risdate>2009</risdate><volume>47</volume><issue>23</issue><spage>6619</spage><epage>6629</epage><pages>6619-6629</pages><issn>0887-624X</issn><issn>1099-0518</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>In this article, we present the synthesis and characterization of water-soluble polymers with hydrophobic moieties. 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| language | eng |
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| subjects | Applied sciences Backbone Cadmium sulfides calorimetry Copolymerization Copolymers cyclodextrins Exact sciences and technology host-guest systems Monomers Organic polymers Phenyls Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts radical polymerization Reproduction Solubility supramolecular structures Synthesis |
| title | Use of β-cyclodextrins to control the structure of water-soluble copolymers with hydrophobic parts |
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