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Anodic behaviour of a metallic U–Pu–Zr alloy during electrorefining process
Electrorefining tests of the non-irradiated U–Pu–Zr alloy were performed in LiCl–KCl–UCl 3–PuCl 3–ZrCl 4 melts at 773 K, aiming at reduced Zr dissolution. The tests were carried out both using potentiostatic electrolysis at −1.0 V (vs. Ag +/Ag), i.e. at a more negative potential than the Zr dissolut...
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| Published in: | Journal of nuclear materials 2011-07, Vol.414 (2), p.194-199 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c371t-61c152c55dca401f5f6925326efa10cd3ad0d9685e69cf86b98aa6184f89435d3 |
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| cites | cdi_FETCH-LOGICAL-c371t-61c152c55dca401f5f6925326efa10cd3ad0d9685e69cf86b98aa6184f89435d3 |
| container_end_page | 199 |
| container_issue | 2 |
| container_start_page | 194 |
| container_title | Journal of nuclear materials |
| container_volume | 414 |
| creator | Murakami, T. Sakamura, Y. Akiyama, N. Kitawaki, S. Nakayoshi, A. Fukushima, M. |
| description | Electrorefining tests of the non-irradiated U–Pu–Zr alloy were performed in LiCl–KCl–UCl
3–PuCl
3–ZrCl
4 melts at 773
K, aiming at reduced Zr dissolution. The tests were carried out both using potentiostatic electrolysis at −1.0
V (vs. Ag
+/Ag), i.e. at a more negative potential than the Zr dissolution potential, and galvanostatic electrolysis with a limited amount of Zr dissolution. The ICP–AES analysis of the anode residues confirmed that a high dissolution yield of actinides (U: >99.6%, Pu: 99.9%) was successfully demonstrated for both electrolyses. |
| doi_str_mv | 10.1016/j.jnucmat.2011.03.009 |
| format | article |
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3–PuCl
3–ZrCl
4 melts at 773
K, aiming at reduced Zr dissolution. The tests were carried out both using potentiostatic electrolysis at −1.0
V (vs. Ag
+/Ag), i.e. at a more negative potential than the Zr dissolution potential, and galvanostatic electrolysis with a limited amount of Zr dissolution. The ICP–AES analysis of the anode residues confirmed that a high dissolution yield of actinides (U: >99.6%, Pu: 99.9%) was successfully demonstrated for both electrolyses.</description><identifier>ISSN: 0022-3115</identifier><identifier>EISSN: 1873-4820</identifier><identifier>DOI: 10.1016/j.jnucmat.2011.03.009</identifier><identifier>CODEN: JNUMAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Controled nuclear fusion plants ; Energy ; Energy. Thermal use of fuels ; Exact sciences and technology ; Fission nuclear power plants ; Fuels ; Installations for energy generation and conversion: thermal and electrical energy ; Nuclear fuels</subject><ispartof>Journal of nuclear materials, 2011-07, Vol.414 (2), p.194-199</ispartof><rights>2011 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c371t-61c152c55dca401f5f6925326efa10cd3ad0d9685e69cf86b98aa6184f89435d3</citedby><cites>FETCH-LOGICAL-c371t-61c152c55dca401f5f6925326efa10cd3ad0d9685e69cf86b98aa6184f89435d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23930,23931,25140,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24463078$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Murakami, T.</creatorcontrib><creatorcontrib>Sakamura, Y.</creatorcontrib><creatorcontrib>Akiyama, N.</creatorcontrib><creatorcontrib>Kitawaki, S.</creatorcontrib><creatorcontrib>Nakayoshi, A.</creatorcontrib><creatorcontrib>Fukushima, M.</creatorcontrib><title>Anodic behaviour of a metallic U–Pu–Zr alloy during electrorefining process</title><title>Journal of nuclear materials</title><description>Electrorefining tests of the non-irradiated U–Pu–Zr alloy were performed in LiCl–KCl–UCl
3–PuCl
3–ZrCl
4 melts at 773
K, aiming at reduced Zr dissolution. The tests were carried out both using potentiostatic electrolysis at −1.0
V (vs. Ag
+/Ag), i.e. at a more negative potential than the Zr dissolution potential, and galvanostatic electrolysis with a limited amount of Zr dissolution. The ICP–AES analysis of the anode residues confirmed that a high dissolution yield of actinides (U: >99.6%, Pu: 99.9%) was successfully demonstrated for both electrolyses.</description><subject>Applied sciences</subject><subject>Controled nuclear fusion plants</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Exact sciences and technology</subject><subject>Fission nuclear power plants</subject><subject>Fuels</subject><subject>Installations for energy generation and conversion: thermal and electrical energy</subject><subject>Nuclear fuels</subject><issn>0022-3115</issn><issn>1873-4820</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkM1KAzEQx4MoWKuPIOxFPO062WzS7ElK8QsK9WAvXkKaD82y3dRkV-jNd_ANfRJTWrx6mWGG_8x_5ofQJYYCA2Y3TdF0g1rLvigB4wJIAVAfoRHmE5JXvIRjNAIoy5xgTE_RWYwNANAa6Agtpp3XTmUr8y4_nR9C5m0ms7XpZdum_vLn6_t5SOE1ZKnjt5keguveMtMa1QcfjHXdrt4Er0yM5-jEyjaai0Meo-X93cvsMZ8vHp5m03muyAT3OcMK01JRqpWsAFtqWV1SUjJjJQalidSga8apYbWynK1qLiXDvLK8rgjVZIyu93uT78dgYi_WLirTtrIzfoiiTmA4pcCSku6VKvgY071iE9xahq3AIHb8RCMO_MSOnwAiEr80d3VwkFHJ1gbZKRf_hsuqYgQmPOlu9zqT3v10JoionOmU0S4kREJ794_TL_4tisQ</recordid><startdate>20110715</startdate><enddate>20110715</enddate><creator>Murakami, T.</creator><creator>Sakamura, Y.</creator><creator>Akiyama, N.</creator><creator>Kitawaki, S.</creator><creator>Nakayoshi, A.</creator><creator>Fukushima, M.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope></search><sort><creationdate>20110715</creationdate><title>Anodic behaviour of a metallic U–Pu–Zr alloy during electrorefining process</title><author>Murakami, T. ; Sakamura, Y. ; Akiyama, N. ; Kitawaki, S. ; Nakayoshi, A. ; Fukushima, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c371t-61c152c55dca401f5f6925326efa10cd3ad0d9685e69cf86b98aa6184f89435d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Controled nuclear fusion plants</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Exact sciences and technology</topic><topic>Fission nuclear power plants</topic><topic>Fuels</topic><topic>Installations for energy generation and conversion: thermal and electrical energy</topic><topic>Nuclear fuels</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Murakami, T.</creatorcontrib><creatorcontrib>Sakamura, Y.</creatorcontrib><creatorcontrib>Akiyama, N.</creatorcontrib><creatorcontrib>Kitawaki, S.</creatorcontrib><creatorcontrib>Nakayoshi, A.</creatorcontrib><creatorcontrib>Fukushima, M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><jtitle>Journal of nuclear materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Murakami, T.</au><au>Sakamura, Y.</au><au>Akiyama, N.</au><au>Kitawaki, S.</au><au>Nakayoshi, A.</au><au>Fukushima, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anodic behaviour of a metallic U–Pu–Zr alloy during electrorefining process</atitle><jtitle>Journal of nuclear materials</jtitle><date>2011-07-15</date><risdate>2011</risdate><volume>414</volume><issue>2</issue><spage>194</spage><epage>199</epage><pages>194-199</pages><issn>0022-3115</issn><eissn>1873-4820</eissn><coden>JNUMAM</coden><abstract>Electrorefining tests of the non-irradiated U–Pu–Zr alloy were performed in LiCl–KCl–UCl
3–PuCl
3–ZrCl
4 melts at 773
K, aiming at reduced Zr dissolution. The tests were carried out both using potentiostatic electrolysis at −1.0
V (vs. Ag
+/Ag), i.e. at a more negative potential than the Zr dissolution potential, and galvanostatic electrolysis with a limited amount of Zr dissolution. The ICP–AES analysis of the anode residues confirmed that a high dissolution yield of actinides (U: >99.6%, Pu: 99.9%) was successfully demonstrated for both electrolyses.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnucmat.2011.03.009</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-3115 |
| ispartof | Journal of nuclear materials, 2011-07, Vol.414 (2), p.194-199 |
| issn | 0022-3115 1873-4820 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_901685506 |
| source | Elsevier:Jisc Collections:Elsevier Read and Publish Agreement 2022-2024:Freedom Collection (Reading list) |
| subjects | Applied sciences Controled nuclear fusion plants Energy Energy. Thermal use of fuels Exact sciences and technology Fission nuclear power plants Fuels Installations for energy generation and conversion: thermal and electrical energy Nuclear fuels |
| title | Anodic behaviour of a metallic U–Pu–Zr alloy during electrorefining process |
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