Preconcentration/Cleanup Studies of Tin from Environmental Water Samples by Oxidized Multiwall Carbon Nanotubes Packed Column and its Determination by ETAAS

• Published in: Water, air, and soil pollution air, and soil pollution, 2011-05, Vol.217 (1-4), p.557-565
• Main Authors: Costa, Heloisa Helena Vilela, de Fátima Lima, Giovana, Nacano, Letícia R., Tarley, César Ricardo Teixeira
• Format: Article
• Language: English
• Subjects: Acetates; Acetic acid; Acids; Adsorption; Analytical chemistry; Applied sciences; Atmospheric Protection/Air Quality Control/Air Pollution; Atomic absorption spectroscopy; Binding sites; Buffers; Cadmium; Carbon; Chemistry; Cleaning; Climate Change/Climate Change Impacts; Earth and Environmental Science; Environment; Environmental cleanup; Environmental monitoring; Exact sciences and technology; Flow rate; Flow rates; Hydrogeology; Interference; Methods; Multi wall carbon nanotubes; Nanotechnology; Nanotubes; Natural waters; Pollution; Polyethylene; Scientific imaging; Soil Science & Conservation; Spectral analysis; Spectrometric and optical methods; Spectrometry; Studies; Tin; Water; Water analysis; Water pollution; Water Quality/Water Pollution; Water sampling
• ISSN: 0049-6979; 1573-2932
• DOI: 10.1007/s11270-010-0609-4

The use of multiwall carbon nanotubes (MWCNT) as an efficient solid extractor in preconcentration/cleanup studies for tin determination in water samples by electrothermal atomic absorption spectrometry (ETAAS) is proposed. In the proposed method, tin adsorption onto MWCNT was carried out by percolating the solution previously buffered (pH 4.79 with 0.24 mol L −1 acetic acid/acetate buffer) at 4.0-mL min −1 flow rate, followed by elution with 1.0 mL of 2.7 mol L −1 HNO 3 . Factors such as sample pH, preconcentration/cleanup flow rate, type and concentration of eluent, and buffer concentration were appraised and optimized from chemometric tools based on fractional factorial design and Doehlert design. A limit of detection of 0.73 μg L −1 and precision ( n  = 8) assessed as relative standard deviation of 8.6% and 7.0% for tin concentration of 8.0 and 43.0 μg L −1 , respectively, were achieved. Foreign metallic ions (Ni 2+ , Pb 2+ , Co 2+ , Zn 2+ , Cd 2+ , Mn 2+ , and Fe 3+ ) were checked as potential interferents, and no interference was observed up to an analyte/interference ratio of 1:10 ( m / v ). Direct tin determination by ETAAS in water samples containing high salt amount is drastically affected by background signal. However, previous cleanup of sample by MWCNT has promoted a significant improvement and makes the method useful for tin monitoring in water samples (mineral, lake, mine, and natural waters) by ETAAS. Quantitative recovery values ranging from 91.5% to 103.0% attested the applicability of the proposed preconcentration/cleanup for tin determination in water samples.