Solid-State Structural Transformations from 2D Interdigitated Layers to 3D Interpenetrated Structures

Construction by shining light! A [2+2] cycloaddition reaction in a 2D coordination polymer accompanied by single‐crystal‐to‐single‐crystal structural transformation to a 3D structure highlights the retrosynthesis of a 3D structure from a 2D layer compound (see scheme, Zn red, 4‐styrylpyridine blue/t...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2011-11, Vol.50 (46), p.10949-10952
Main Authors: Medishetty, Raghavender, Koh, Lip Lin, Kole, Goutam Kumar, Vittal, Jagadese J.
Format: Article
Language:English
Subjects:
isostructural ligands
metal-organic frameworks
photo cycloaddition
single-crystal-to-single-crystal transformation
zinc
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Summary:Construction by shining light! A [2+2] cycloaddition reaction in a 2D coordination polymer accompanied by single‐crystal‐to‐single‐crystal structural transformation to a 3D structure highlights the retrosynthesis of a 3D structure from a 2D layer compound (see scheme, Zn red, 4‐styrylpyridine blue/turquoise).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201104106