Determination of RE@d2Ce@d2O@d7 pyrochlore phases from monazite-allanite ores

• Published in: Hydrometallurgy 2009-07, Vol.97 (3-4), p.167-172
• Main Authors: Bezerra Lopes, F.W., de Souza, C.P., Vieira de Morais, A.M., Dallas, J P, Gavarri, J R
• Format: Article
• Language: English
• ISSN: 0304-386X
• DOI: 10.1016/j.hydromet.2009.02.007

By using a specific chemical process, it was possible to extract a pyrochlore RE@d2Ce@d2O@d7 phase directly from waste materials composed of allanite-monazite minerals mixed with aluminosilicate and other phosphate phases. The pyrochlore phase is well known for its interesting thermal properties. Monazite (Ce, La, Nd, Pr, Th) PO@d4 is a mineral rich in rare earth elements (cerium, lanthanum). Polycrystalline waste samples were submitted to a series of chemical treatments followed by alkaline fusion. After reaction with nitric acid and addition of oxalic acid, soluble ions were separated from insoluble ones, resulting in rare earth oxalate intermediate phases. After filtration, these oxalate phases were dried and heated at 900 @uoC. The resulting solid was analyzed by transmission electron microscopy and X-ray diffraction. These analyses showed that the as-extracted phase was composed of a complex RE@d2@u3@u+Ce@d2@u4@u+O@d7@u2@u- system, rich in cerium and lanthanum along with other rare earth elements (RE). The mean crystal structure of these complex phases was determined from Rietveld diffraction profile refinement; it was close to pyrochlore structure La@d2Ce@d2O@d7 with space group Fd3m. The refined cell parameter a, and the lattice distortion ?, calculated from profile broadening analyses, were related to the presence of RE@u3@u+ ions occupying the La site.