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New anthracene-containing phenylene- or thienylene-vinylene copolymers: Synthesis, characterization, photophysics, and photovoltaics
Four new conjugated alternating vinylene-copolymers, PAP6, PAT, PA, and TAT, incorporating anthracene rings along the backbone were synthesized by Heck coupling. They were very soluble in common organic solvents and absorbed at the range of 300-500 nm with optical band gaps of 2.38-2.47 eV. They beh...
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| Published in: | Journal of applied polymer science 2009-07, Vol.113 (2), p.1173-1181 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c4567-be5c022bd080973ec19104f91b0c4721b98f7fc3cf6f62b2d066c0b78d54b25a3 |
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| cites | cdi_FETCH-LOGICAL-c4567-be5c022bd080973ec19104f91b0c4721b98f7fc3cf6f62b2d066c0b78d54b25a3 |
| container_end_page | 1181 |
| container_issue | 2 |
| container_start_page | 1173 |
| container_title | Journal of applied polymer science |
| container_volume | 113 |
| creator | Vellis, Panagiotis D Mikroyannidis, John A Bagnis, Diego Valentini, Luca Kenny, Josè M |
| description | Four new conjugated alternating vinylene-copolymers, PAP6, PAT, PA, and TAT, incorporating anthracene rings along the backbone were synthesized by Heck coupling. They were very soluble in common organic solvents and absorbed at the range of 300-500 nm with optical band gaps of 2.38-2.47 eV. They behaved in solution as green emitters, with maximum photoluminescence at 455-518 nm. Finally, these soluble copolymers were used as donor material to realize bulk heterojunction solar cell with (6,6)-C₆₁-butyric acid methyl ester as the acceptor. More efficient photovoltaic cells were obtained from the copolymer that carried hexyloxy than dodecyloxy side groups. |
| doi_str_mv | 10.1002/app.29967 |
| format | article |
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They were very soluble in common organic solvents and absorbed at the range of 300-500 nm with optical band gaps of 2.38-2.47 eV. They behaved in solution as green emitters, with maximum photoluminescence at 455-518 nm. Finally, these soluble copolymers were used as donor material to realize bulk heterojunction solar cell with (6,6)-C₆₁-butyric acid methyl ester as the acceptor. 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Appl. Polym. Sci</addtitle><description>Four new conjugated alternating vinylene-copolymers, PAP6, PAT, PA, and TAT, incorporating anthracene rings along the backbone were synthesized by Heck coupling. They were very soluble in common organic solvents and absorbed at the range of 300-500 nm with optical band gaps of 2.38-2.47 eV. They behaved in solution as green emitters, with maximum photoluminescence at 455-518 nm. Finally, these soluble copolymers were used as donor material to realize bulk heterojunction solar cell with (6,6)-C₆₁-butyric acid methyl ester as the acceptor. More efficient photovoltaic cells were obtained from the copolymer that carried hexyloxy than dodecyloxy side groups.</description><subject>anthracene</subject><subject>Applied sciences</subject><subject>Copolymers</subject><subject>Energy gaps (solid state)</subject><subject>Esters</subject><subject>Exact sciences and technology</subject><subject>Heterojunctions</subject><subject>Organic polymers</subject><subject>PAT</subject><subject>phenylenevinylene</subject><subject>photophysics</subject><subject>Photovoltaic cells</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Solar cells</subject><subject>Solvents</subject><subject>synthesis</subject><subject>thienylenevinylene</subject><issn>0021-8995</issn><issn>1097-4628</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkU1v1DAQQC0EEkvhwC8gF0BITeuxHTvurapoQVqWim3F0XK8TmPI2sFOP8KZH45L2t6Ak-2ZN2_GGoReAt4DjMm-HoY9IiUXj9ACsBQl46R-jBY5B2UtZfUUPUvpG8YAFeYL9Gtlrwvtxy5qY70tTfCjdt75i2LorJ_622ARYjF27v555eZLYcIQ-mlrYzoo1lOW2OTSbmE6nW2jje6nHl3wu1kVxjB0U3Im57XfzJGr0OdmJj1HT1rdJ_vi7txB58fvz44-lMvPJx-PDpelYRUXZWMrgwlpNrjOP6PWgATMWgkNNkwQaGTditZQ0_KWk4ZsMOcGN6LeVKwhlaY76O3sHWL4cWnTqLYuGdv32ttwmZTElFMiZP1fspYchMj9M_nmnyRljFHCeQbfzaCJIaVoWzVEt9VxUoDV7e5U3p36s7vMvr6T6mR030btjUsPBQQqwiVhmdufuWvX2-nvQnV4enpvLucKl0Z781Ch43eVs6JSX1cnClbLT1-YXKuzzL-a-VYHpS9inuJ8TTBQDJxQEEB_A2O_w0E</recordid><startdate>20090715</startdate><enddate>20090715</enddate><creator>Vellis, Panagiotis D</creator><creator>Mikroyannidis, John A</creator><creator>Bagnis, Diego</creator><creator>Valentini, Luca</creator><creator>Kenny, Josè M</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20090715</creationdate><title>New anthracene-containing phenylene- or thienylene-vinylene copolymers: Synthesis, characterization, photophysics, and photovoltaics</title><author>Vellis, Panagiotis D ; Mikroyannidis, John A ; Bagnis, Diego ; Valentini, Luca ; Kenny, Josè M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4567-be5c022bd080973ec19104f91b0c4721b98f7fc3cf6f62b2d066c0b78d54b25a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>anthracene</topic><topic>Applied sciences</topic><topic>Copolymers</topic><topic>Energy gaps (solid state)</topic><topic>Esters</topic><topic>Exact sciences and technology</topic><topic>Heterojunctions</topic><topic>Organic polymers</topic><topic>PAT</topic><topic>phenylenevinylene</topic><topic>photophysics</topic><topic>Photovoltaic cells</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Solar cells</topic><topic>Solvents</topic><topic>synthesis</topic><topic>thienylenevinylene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vellis, Panagiotis D</creatorcontrib><creatorcontrib>Mikroyannidis, John A</creatorcontrib><creatorcontrib>Bagnis, Diego</creatorcontrib><creatorcontrib>Valentini, Luca</creatorcontrib><creatorcontrib>Kenny, Josè M</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vellis, Panagiotis D</au><au>Mikroyannidis, John A</au><au>Bagnis, Diego</au><au>Valentini, Luca</au><au>Kenny, Josè M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New anthracene-containing phenylene- or thienylene-vinylene copolymers: Synthesis, characterization, photophysics, and photovoltaics</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2009-07-15</date><risdate>2009</risdate><volume>113</volume><issue>2</issue><spage>1173</spage><epage>1181</epage><pages>1173-1181</pages><issn>0021-8995</issn><issn>1097-4628</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Four new conjugated alternating vinylene-copolymers, PAP6, PAT, PA, and TAT, incorporating anthracene rings along the backbone were synthesized by Heck coupling. They were very soluble in common organic solvents and absorbed at the range of 300-500 nm with optical band gaps of 2.38-2.47 eV. They behaved in solution as green emitters, with maximum photoluminescence at 455-518 nm. Finally, these soluble copolymers were used as donor material to realize bulk heterojunction solar cell with (6,6)-C₆₁-butyric acid methyl ester as the acceptor. More efficient photovoltaic cells were obtained from the copolymer that carried hexyloxy than dodecyloxy side groups.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.29967</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of applied polymer science, 2009-07, Vol.113 (2), p.1173-1181 |
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| language | eng |
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| source | Wiley-Blackwell Read & Publish Collection |
| subjects | anthracene Applied sciences Copolymers Energy gaps (solid state) Esters Exact sciences and technology Heterojunctions Organic polymers PAT phenylenevinylene photophysics Photovoltaic cells Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Solar cells Solvents synthesis thienylenevinylene |
| title | New anthracene-containing phenylene- or thienylene-vinylene copolymers: Synthesis, characterization, photophysics, and photovoltaics |
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