New seven membered palladacycles: C-Br bond activation of 2-bromo-pyridine derivative by Pd(II)

C-Br bond activation followed by a C-C coupling reaction of the 2-bromo-pyridyl unit of [1-phenyl-2-(6-bromopyridin-2-yl)-benzoimidazole] was performed by Pd(CH(2)CMe(2)-o-C(6)H(4))(η(4)-COD). Two new seven membered palladacycles were obtained. A combined experimental and theoretical DFT study eluci...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2011-01, Vol.40 (46), p.12450-12453
Main Authors: Nicasio-Collazo, Juan, Álvarez, Eleuterio, Alvarado-Monzón, José C, Andreu-de-Riquer, Gabriel, Jimenez-Halla, J Oscar C, De León-Rodríguez, Luis M, Merino, Gabriel, Morales, Ubaldo, Serrano, Oracio, López, Jorge A
Format: Article
Language:English
Subjects:
Activation
Bonding
Carbon-carbon composites
Derivatives
Joining
Prints
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Summary:C-Br bond activation followed by a C-C coupling reaction of the 2-bromo-pyridyl unit of [1-phenyl-2-(6-bromopyridin-2-yl)-benzoimidazole] was performed by Pd(CH(2)CMe(2)-o-C(6)H(4))(η(4)-COD). Two new seven membered palladacycles were obtained. A combined experimental and theoretical DFT study elucidates the mechanism for this reaction.
ISSN:1477-9226
1477-9234
DOI:10.1039/c1dt11451d