Selective Catalytic Hydrogenation of Nitro Groups in the Presence of Activated Heteroaryl Halides

Chemoselective reduction of nitro groups in the presence of activated heteroaryl halides was achieved via catalytic hydrogenation with a commercially available sulfided platinum catalyst. The optimized conditions employ low temperature, pressure, and catalyst loading (

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Bibliographic Details
Published in:Journal of organic chemistry 2011-12, Vol.76 (23), p.9841-9844
Main Authors: Kasparian, Annie J, Savarin, Cecile, Allgeier, Alan M, Walker, Shawn D
Format: Article
Language:English
Subjects:
Amines - chemical synthesis
Amines - chemistry
Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
Heterocyclic compounds
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Hydrocarbons, Halogenated - chemistry
Hydrogenation
Molecular Structure
Organic chemistry
Preparations and properties
Stereoisomerism
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Description
Summary:Chemoselective reduction of nitro groups in the presence of activated heteroaryl halides was achieved via catalytic hydrogenation with a commercially available sulfided platinum catalyst. The optimized conditions employ low temperature, pressure, and catalyst loading (
ISSN:0022-3263
1520-6904
DOI:10.1021/jo2015664