A mild and environmentally benign method for the synthesis of glycals in PEG-600/H2O

Glycals were synthesized via a simple, mild, convenient and environmentally benign procedure, in which protected glycosyl bromides undergo the reductive elimination in the presence of zinc in PEG-600/H2O at room temperature. The glycals were obtained in 75-92% isolated yields.

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2009-01, Vol.11 (8), p.1124-1127
Main Authors: Zhao, Jinzhong, Wei, Shanqiao, Ma, Xiaofeng, Shao, Huawu
Format: Article
Language:English
Subjects:
Temperature
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Summary:Glycals were synthesized via a simple, mild, convenient and environmentally benign procedure, in which protected glycosyl bromides undergo the reductive elimination in the presence of zinc in PEG-600/H2O at room temperature. The glycals were obtained in 75-92% isolated yields.
ISSN:1463-9262
1463-9270
DOI:10.1039/b821681a