Selective photocatalytic reductions of nitrobenzene derivatives using PbBiO2X and blue light

Blue light irradiation of heterogeneous photocatalysts PbBiO2X (X = Cl, Br) in the presence of triethanolamine as an electron donor leads to hydrogen evolution, and the selective, clean and complete reduction of nitrobenzene derivatives to their corresponding anilines.

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2011-01, Vol.13 (3), p.640-643
Main Authors: FÜLDNER, Stefan, POHLA, Patrick, BARTLING, Hanna, DANKESREITER, Stephan, STADLER, Roland, GRUBER, Michael, PFITZNER, Arno, KÖNIG, Burkhard
Format: Article
Language:English
Subjects:
Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
Hydrogen
Noncondensed benzenic compounds
Organic chemistry
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Preparations and properties
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:Blue light irradiation of heterogeneous photocatalysts PbBiO2X (X = Cl, Br) in the presence of triethanolamine as an electron donor leads to hydrogen evolution, and the selective, clean and complete reduction of nitrobenzene derivatives to their corresponding anilines.
ISSN:1463-9262
1463-9270
DOI:10.1039/c0gc00857e