Synthesis and dielectric characterization of Ba0.6Sr0.4TiO3 ferroelectric ceramics

• Published in: Thin solid films 2011-06, Vol.519 (17), p.5811-5815
• Main Authors: NEDELCU, L, IOACHIM, A, TOACSAN, M, BANCIU, M. G, PASUK, I, BERBECARU, C, ALEXANDRU, H. V
• Format: Article
• Language: English
• Subjects: Barium strontium titanates; Ceramics; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Dielectric constant; Dielectric loss; Exact sciences and technology; Materials science; Methods of deposition of films and coatings; film growth and epitaxy; Permittivity; Physics; Raw materials; Sintering; Structure and morphology; thickness; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties); Theory and models of film growth; Thin film structure and morphology
• ISSN: 0040-6090; 1879-2731
• DOI: 10.1016/j.tsf.2010.12.191

Ferroelectric ceramics Ba0.6Sr0.4TiO3 (BST 40) were prepared, by solid-state reaction in the temperature range 1210-1450 degree C. Maximum values of the ceramic densities were around 94% of their theoretical value. X-ray diffraction techniques (XRD) and scanning electron spectroscopy (SEM) were used to analyze the structure and the surface morphology of ceramics. Rounded, well defined or abnormal granular growth was observed in the SEM images, vs. sintering conditions and purity of the raw materials. In all samples, BST 40 ceramic is the major phase, but there are also present small amounts of secondary phases, as revealed in XRD diffraction patterns. Permittivity and dielectric loss measurements were performed in the temperature range -150 to +150 degree C, and 150Hz-5MHz frequency values. Permittivity values rising from 1200 to 12,500, with increasing sintering temperatures, were recorded. Narrow and well defined transition peaks were noticed at higher sintering temperatures. Curie temperature was around 2 degree C, for samples with the mentioned composition. Permittivity and losses vs. frequency show different behavior whether BST ceramics are in polar or non-polar state and with the distance toward phase transition. Microwave measurements performed at room temperature have shown lower values of permittivity, compared with similar data at low frequency, and dielectric losses lower than 1% at 0.7GHz. The sintering conditions (temperatures, sintering time, etc.) and purity of the raw materials lead to important changes of transition temperatures in the polymorphic diagram, which we have built-for the other Ba1-xSrxTiO3 compositions (x=0.25-0.90) sintered at 1260 degree C for 2h.