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Durability of nitrided fluorocarbon polymer films for nanoimprint lithography

Hydrophobic fluorocarbon polymer films have been used as anti-sticking and releasing coatings for templates in nano-imprint lithography, but have poor durability against repeated high pressure pressing processes. The addition of nitrogen into fluorocarbon-based gas plasma can provide nitrided fluoro...

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Bibliographic Details
Published in:Thin solid films 2011-06, Vol.519 (16), p.5490-5493
Main Authors: Kim, Han-Hyoung, Park, Se-Geun, Lee, El-Hang, Lee, Seung-Gol, O, Beom-Hoan
Format: Article
Language:English
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Summary:Hydrophobic fluorocarbon polymer films have been used as anti-sticking and releasing coatings for templates in nano-imprint lithography, but have poor durability against repeated high pressure pressing processes. The addition of nitrogen into fluorocarbon-based gas plasma can provide nitrided fluorocarbon polymer films, as confirmed by Fourier-transform infrared spectroscopy. Fluorocarbon and nitrided fluorocarbon films have almost the same 110.0° contact angle with water drops. The nitrided fluorocarbon films are harder and significantly enhance durability as anti-sticking layers. Durability enhancement has been confirmed by fabricating replicas with silicon templates using nitrided fluorocarbon anti-sticking layers.
ISSN:0040-6090
1879-2731
DOI:10.1016/j.tsf.2011.03.124