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Interfacial reactions between eutectic Sn–Pb solder and Co substrate

This study examined the reaction couples of Co substrate with liquid and solid Sn-37 wt% Pb alloys, respectively. In the liquid/solid Sn–Pb/Co couples, one single-phase CoSn 3 layer was found at the interface at temperatures from 210 to 250 °C. The layer thickness was measured as a function of the r...

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Published in:Journal of materials science 2011-04, Vol.46 (8), p.2654-2661
Main Authors: Wang, Chao-hong, Kuo, Chun-yi
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Language:English
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description This study examined the reaction couples of Co substrate with liquid and solid Sn-37 wt% Pb alloys, respectively. In the liquid/solid Sn–Pb/Co couples, one single-phase CoSn 3 layer was found at the interface at temperatures from 210 to 250 °C. The layer thickness was measured as a function of the reaction time. The layer growth rate increased with increasing temperature. The CoSn 3 layer growth was linear in the early stage and then became parabolic. In addition, the similar CoSn 3 growth behavior results were observed in the solid/solid Sn–Pb/Co couples from 150 to 170 °C. Nevertheless, one Pb-rich phase layer accumulated at the solder/CoSn 3 interface due to Sn consumption. Also, the reaction kinetics of Sn-37 wt% Pb/Co was symmetrically studied at various temperatures. The chemical reaction constants, diffusion constants, and the relevant activation energies were reported.
doi_str_mv 10.1007/s10853-010-5121-0
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subjects Activation energy
Alloys
Characterization and Evaluation of Materials
Chemical reaction, Rate of
Chemical reactions
Chemistry and Materials Science
Classical Mechanics
Constants
Crystallography and Scattering Methods
Eutectic reactions
Interface reactions
Lead
Materials Science
Organic chemistry
Polymer Sciences
Reaction kinetics
Reaction time
Solid Mechanics
Substrates
Thickness measurement
title Interfacial reactions between eutectic Sn–Pb solder and Co substrate
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