Luminescence and EPR studies of Y2O3:Gd3+ phosphors prepared via solution combustion method

• Published in: Journal of materials science 2011-02, Vol.46 (4), p.1038-1043
• Main Authors: Singh, Vijay, Chakradhar, R. P. S., Rao, J. L., Ledoux-Rak, Isabelle, Kwak, Ho-Young
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Classical Mechanics; Combustion; Crystallography and Scattering Methods; Diffraction; Emission; Gadolinium; Luminescence; Materials Science; Phosphors; Polymer Sciences; Scanning electron microscopy; Solid Mechanics; Symmetry; Ultraviolet radiation; X-rays; Yttrium oxide
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-010-4869-6

Gadolinium-activated Y 2 O 3 phosphor has been prepared by combustion process in a short time of 5 min. The phosphors are well characterized by X-ray diffraction, scanning electron microscopy, and energy-dispersive analysis of X-ray. The as-prepared Y 2 O 3 :Gd powder shows that all the peaks are due to the Y 2 O 3 cubic phase. Upon UV light excitation (276 nm), the phosphor exhibits a strong and sharp UV emission at 314 nm and is ascribed to transition of Gd 3+ ions. The EPR spectrum of Y 2 O 3 :Gd phosphor exhibits resonance signals with effective g values at g  = 1.96, g  = 2.88, and g  = 6.08 and are attributed to Gd 3+ ions located at sites with weak, intermediate, and strong cubic symmetry fields, respectively. It is observed that the population of spin levels (N) and linewidth depends on temperature. The paramagnetic susceptibility (χ) is also evaluated as a function of temperature and discussed.