Coordination-driven self-assembly of polyoxometalates into discrete supramolecular triangles

Pd(II)-directed self-assembly of a 3-pyridyl grafted Lindqvist hexavanadate led to the formation of a unique trimeric species, as confirmed by a variety of techniques, including pulsed-field gradient NMR spectroscopy and high-resolution ESI mass spectrometry.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (2), p.200-202
Main Authors: Santoni, Marie-Pierre, Pal, Amlan K, Hanan, Garry S, Tang, Marie-Christine, Venne, Karine, Furtos, Alexandra, Ménard-Tremblay, Pierre, Malveau, Cédric, Hasenknopf, Bernold
Format: Article
Language:English
Subjects:
Grafting
Mass spectrometry
NMR spectroscopy
Self assembly
Triangles
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Description
Summary:Pd(II)-directed self-assembly of a 3-pyridyl grafted Lindqvist hexavanadate led to the formation of a unique trimeric species, as confirmed by a variety of techniques, including pulsed-field gradient NMR spectroscopy and high-resolution ESI mass spectrometry.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc16155e