Consecutive Molecular Crystalline-State Reactions with Metal Complexes

Engineering crystals: Molecular single crystals of well‐defined metal complexes selectively and reversibly undergo ligand‐exchange reactions. These results are a prelude to sensing and new catalytic reactions within the confined space of a crystal lattice.

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2011-12, Vol.50 (50), p.11846-11848
Main Author: van der Boom, Milko E
Format: Article
Language:English
Subjects:
Catalysis
Catalysts
coordination chemistry
crystal engineering
Crystal lattices
Crystal structure
Crystals
Detection
Single crystals
transition metals
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Description
Summary:Engineering crystals: Molecular single crystals of well‐defined metal complexes selectively and reversibly undergo ligand‐exchange reactions. These results are a prelude to sensing and new catalytic reactions within the confined space of a crystal lattice.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201105940