Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (5), p.663-665
Main Authors: Dragässer, André, Shekhah, Osama, Zybaylo, Olexandra, Shen, Cai, Buck, Manfred, Wöll, Christof, Schlettwein, Derck
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc16580a