From 1D to 3D Single-Crystal-to-Single-Crystal Structural Transformations Based on Linear Polyanion [Mn4(H2O)18WZnMn2(H2O)2(ZnW9O34)2]4

A 1D anionic polyoxometalate, [Mn4(H2O)18WZnMn2(H2O)2(ZnW9O34)2]4–, undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co2+ and Cu2+) and solvent molecules. These solid materials present interesting catalytic activity for the...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2011-12, Vol.50 (24), p.12387-12389
Main Authors: Shi, Lian-Xu, Zhao, Wen-Feng, Xu, Xuan, Tang, Jing, Wu, Chuan-De
Format: Article
Language:English
Subjects:
Catalysis
Cations
Cobalt - chemistry
Copper - chemistry
Crystallization
Crystallography, X-Ray
Dihydropyridines - chemistry
Models, Molecular
Oxidation-Reduction
Polymers - chemistry
Tungsten Compounds - chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A 1D anionic polyoxometalate, [Mn4(H2O)18WZnMn2(H2O)2(ZnW9O34)2]4–, undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co2+ and Cu2+) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1,4-dihydropyridines that is dependent on the inserted heterogeneous metal cations.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic2020572