Cationic terminal hydrido rare earth complexes bearing an amidinate ancillary ligand

The first well defined cationic terminal hydrido rare earth complexes [(NCN)LnH(THF)(3)][BPh(4)] were isolated from THF, which on recrystallization from chlorobenzene gave reversibly the novel dicationic binuclear dihydride complexes [(NCN)Ln(μ-H)(THF)(2)](2)[BPh(4)](2).

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (6), p.814-816
Main Authors: Cheng, Jianhua, Hou, Zhaomin
Format: Article
Language:English
Subjects:
Bearing
Cationic
Chlorobenzenes
Dihydrides
Ligands
Rare earth metals
Recrystallization
Terminals
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Summary:The first well defined cationic terminal hydrido rare earth complexes [(NCN)LnH(THF)(3)][BPh(4)] were isolated from THF, which on recrystallization from chlorobenzene gave reversibly the novel dicationic binuclear dihydride complexes [(NCN)Ln(μ-H)(THF)(2)](2)[BPh(4)](2).
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc14949k