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Solid State Field-Assisted Diffusion of Copper in Multi-Component Tellurite Glass
In this work, we have prepared copper‐doped multicomponent tellurite glasses by solid state electric field‐assisted diffusion. The concentration profiles of the elements have been measured by the secondary ion mass spectrometry. The depth profile of copper can be well fitted only by a modified erfc‐...
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Published in: | Journal of the American Ceramic Society 2011-07, Vol.94 (7), p.1986-1988 |
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cites | cdi_FETCH-LOGICAL-c4446-94b87a177915a115cadd58d8ed01ab3a19c48cf9f7628a10750fb011bf8a8eeb3 |
container_end_page | 1988 |
container_issue | 7 |
container_start_page | 1986 |
container_title | Journal of the American Ceramic Society |
container_volume | 94 |
creator | Stepanov, Boris Ren, Jing Wagner, Tomas Lorincik, Jan Frumar, Miroslav Churbanov, Mikhail Chigirinsky, Yuri |
description | In this work, we have prepared copper‐doped multicomponent tellurite glasses by solid state electric field‐assisted diffusion. The concentration profiles of the elements have been measured by the secondary ion mass spectrometry. The depth profile of copper can be well fitted only by a modified erfc‐like solution of the second Fick's law which assumes that both the Cu+ and Cu2+ ions are involved in the diffusion. The modeling shows that the Cu2+ ions are much more mobile than the Cu+ ones in the tellurite glasses and affected strongly by the applied electric field. Our results demonstrate the possibility of fabricating copper‐doped planar waveguides based on the tellurite glasses. |
doi_str_mv | 10.1111/j.1551-2916.2011.04606.x |
format | article |
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The concentration profiles of the elements have been measured by the secondary ion mass spectrometry. The depth profile of copper can be well fitted only by a modified erfc‐like solution of the second Fick's law which assumes that both the Cu+ and Cu2+ ions are involved in the diffusion. The modeling shows that the Cu2+ ions are much more mobile than the Cu+ ones in the tellurite glasses and affected strongly by the applied electric field. 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Am. Ceram. Soc</addtitle><description>In this work, we have prepared copper‐doped multicomponent tellurite glasses by solid state electric field‐assisted diffusion. The concentration profiles of the elements have been measured by the secondary ion mass spectrometry. The depth profile of copper can be well fitted only by a modified erfc‐like solution of the second Fick's law which assumes that both the Cu+ and Cu2+ ions are involved in the diffusion. The modeling shows that the Cu2+ ions are much more mobile than the Cu+ ones in the tellurite glasses and affected strongly by the applied electric field. Our results demonstrate the possibility of fabricating copper‐doped planar waveguides based on the tellurite glasses.</description><subject>CERAMICS</subject><subject>Copper</subject><subject>DIFFUSION</subject><subject>Electric fields</subject><subject>Glass</subject><subject>GLASSES</subject><subject>Law</subject><subject>Planar waveguides</subject><subject>Secondary ion mass spectrometry</subject><subject>Solid state</subject><subject>SOLID STATE PHYSICS</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqNkU9v1DAQxS0EEkvhO1hc4JLgcfwvF6QlbRdQAUFLOVpOYktesnGwE7H99jgs6oEDwhd75Pd-mpmHEAZSQj6v9iVwDgWtQZSUAJSECSLK4wO0uf94iDaEEFpIRclj9CSlfS6hVmyDPl-Hwff4ejazxZfeDn2xTcmn2fb43Du3JB9GHBxuwjTZiP2IPyzD7IsmHKYw2nHGN3YYluizfzeYlJ6iR84MyT77c5-hr5cXN83b4urT7l2zvSo6xpgoatYqaUDKGrgB4J3pe656ZXsCpq0M1B1TnaudFFQZIJIT1-b5WqeMsratztCLE3eK4cdi06wPPnW5FzPasCRdAxOUUF5l5ct_KkFIqDiVgmTp87-k-7DEMc-hlWJQSV6vPHUSdTGkFK3TU_QHE-80EL2Govd63b1ed6_XUPTvUPQxW1-frD_9YO_-26ffb5uL9ZkBxQmwRnS8B5j4XQuZ29PfPu60_HJ-e1tJqt9UvwBQXqBa</recordid><startdate>201107</startdate><enddate>201107</enddate><creator>Stepanov, Boris</creator><creator>Ren, Jing</creator><creator>Wagner, Tomas</creator><creator>Lorincik, Jan</creator><creator>Frumar, Miroslav</creator><creator>Churbanov, Mikhail</creator><creator>Chigirinsky, Yuri</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>H8G</scope></search><sort><creationdate>201107</creationdate><title>Solid State Field-Assisted Diffusion of Copper in Multi-Component Tellurite Glass</title><author>Stepanov, Boris ; Ren, Jing ; Wagner, Tomas ; Lorincik, Jan ; Frumar, Miroslav ; Churbanov, Mikhail ; Chigirinsky, Yuri</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4446-94b87a177915a115cadd58d8ed01ab3a19c48cf9f7628a10750fb011bf8a8eeb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>CERAMICS</topic><topic>Copper</topic><topic>DIFFUSION</topic><topic>Electric fields</topic><topic>Glass</topic><topic>GLASSES</topic><topic>Law</topic><topic>Planar waveguides</topic><topic>Secondary ion mass spectrometry</topic><topic>Solid state</topic><topic>SOLID STATE PHYSICS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stepanov, Boris</creatorcontrib><creatorcontrib>Ren, Jing</creatorcontrib><creatorcontrib>Wagner, Tomas</creatorcontrib><creatorcontrib>Lorincik, Jan</creatorcontrib><creatorcontrib>Frumar, Miroslav</creatorcontrib><creatorcontrib>Churbanov, Mikhail</creatorcontrib><creatorcontrib>Chigirinsky, Yuri</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Copper Technical Reference Library</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stepanov, Boris</au><au>Ren, Jing</au><au>Wagner, Tomas</au><au>Lorincik, Jan</au><au>Frumar, Miroslav</au><au>Churbanov, Mikhail</au><au>Chigirinsky, Yuri</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solid State Field-Assisted Diffusion of Copper in Multi-Component Tellurite Glass</atitle><jtitle>Journal of the American Ceramic Society</jtitle><addtitle>J. Am. Ceram. Soc</addtitle><date>2011-07</date><risdate>2011</risdate><volume>94</volume><issue>7</issue><spage>1986</spage><epage>1988</epage><pages>1986-1988</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>In this work, we have prepared copper‐doped multicomponent tellurite glasses by solid state electric field‐assisted diffusion. The concentration profiles of the elements have been measured by the secondary ion mass spectrometry. The depth profile of copper can be well fitted only by a modified erfc‐like solution of the second Fick's law which assumes that both the Cu+ and Cu2+ ions are involved in the diffusion. The modeling shows that the Cu2+ ions are much more mobile than the Cu+ ones in the tellurite glasses and affected strongly by the applied electric field. Our results demonstrate the possibility of fabricating copper‐doped planar waveguides based on the tellurite glasses.</abstract><cop>Columbus</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1551-2916.2011.04606.x</doi><tpages>3</tpages></addata></record> |
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issn | 0002-7820 1551-2916 |
language | eng |
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source | Wiley-Blackwell Read & Publish Collection |
subjects | CERAMICS Copper DIFFUSION Electric fields Glass GLASSES Law Planar waveguides Secondary ion mass spectrometry Solid state SOLID STATE PHYSICS |
title | Solid State Field-Assisted Diffusion of Copper in Multi-Component Tellurite Glass |
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