Molybdenum polyoxometalate buckyballs containing monochloroacetate groups and polymer compositions on their base

Molybdenum polyoxometalate buckyballs (NH₄)₄₂[MO ₇₂ VI MO ₆₀ V O₃₇₂(ClCH₂COO)₃₀(H₂O)₇₂] · 250H₂O · 15ClCH₂COONa (Mo132Cl) were synthesized; some of their properties were studied, namely, purity, spectral and crystallographic parameters, buckyball aggregation in solution, and interaction with water-s...

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Published in:Russian journal of inorganic chemistry 2010, Vol.55 (8), p.1260-1265
Main Authors: Ostroushko, A. A, Tonkushina, M. O, Safronov, A. P, Udilov, A. E
Format: Article
Language:English
Subjects:
Agglomeration
Analogue
Chemistry
Chemistry and Materials Science
Destruction
Heating
Hydroxides
Inorganic Chemistry
Molybdenum
Physical Methods of Investigation
Spectra
Stability
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container_end_page 1265
container_issue 8
container_start_page 1260
container_title Russian journal of inorganic chemistry
container_volume 55
creator Ostroushko, A. A
Tonkushina, M. O
Safronov, A. P
Udilov, A. E
description Molybdenum polyoxometalate buckyballs (NH₄)₄₂[MO ₇₂ VI MO ₆₀ V O₃₇₂(ClCH₂COO)₃₀(H₂O)₇₂] · 250H₂O · 15ClCH₂COONa (Mo132Cl) were synthesized; some of their properties were studied, namely, purity, spectral and crystallographic parameters, buckyball aggregation in solution, and interaction with water-soluble nonionic polymers (poly(vinyl alcohol) and poly(vinylpyrrolidone)). The newly synthesized polyoxometalate was shown to have a lower stability than its analogue containing acetate instead of chloroacetate groups, both having similar thermal destruction pathways. At the first heating steps, water is eliminated from Mo132Cl. Thermal destruction at higher temperature produces chloroacetamide, chloroacetonitrile, and other compounds.
doi_str_mv 10.1134/S0036023610080188
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Thermal destruction at higher temperature produces chloroacetamide, chloroacetonitrile, and other compounds.</description><subject>Agglomeration</subject><subject>Analogue</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Destruction</subject><subject>Heating</subject><subject>Hydroxides</subject><subject>Inorganic Chemistry</subject><subject>Molybdenum</subject><subject>Physical Methods of Investigation</subject><subject>Spectra</subject><subject>Stability</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kUFr3DAQhUVooNskP6Cn-NZe3GokxdIeS2iTQkoPSc5ibI03Tm2NK9nQ_ffVZnsrhDnMwPveg-EJ8R7kJwBtPt9LqRupdANSOgnOnYgNXGmoXQP6jdgc5PqgvxXvcn6W0hhp3UbMP3jct4HiOlVzOfkPT7TgiAtV7dr92rc4jrnqOC44xCHuqokjd08jJ8aukIXbJV7nXGEMLxETpcJPM-dhGTjmimO1PNGQqhYznYvTHsdMF__2mXj89vXh-ra--3nz_frLXd1pa5fayGDsFqzRoaGtw9BbDcEhEaENzpiubwCcCW2PtlfKkTMuALVIre5D0GfiwzF3Tvx7pbz4acgdjSNG4jX7LZhGab21hfz4Kgm2UaCMc1cFhSPaJc45Ue_nNEyY9h6kP_Tg_-uheNTRkwsbd5T8M68plt9fNV0eTT2yx10asn-8VxL0i6rK_AWTCJbG</recordid><startdate>2010</startdate><enddate>2010</enddate><creator>Ostroushko, A. 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source Springer Nature
subjects Agglomeration
Analogue
Chemistry
Chemistry and Materials Science
Destruction
Heating
Hydroxides
Inorganic Chemistry
Molybdenum
Physical Methods of Investigation
Spectra
Stability
title Molybdenum polyoxometalate buckyballs containing monochloroacetate groups and polymer compositions on their base
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