Spectroscopic studies of molybdenum polyoxometallates with the buckyball structure and polymer-containing compositions based thereon

Molybdenum polyoxometallates with the buckyball structure, ((NH 4 ) 42 [Mo 72 VI Mo 60 V O 372 (H 3 CCOO) 30 (H 2 O) 72 ] · 30H 3 CCOONH 4 · 250H 2 O ( I ), (NH 4 ) 42 [Mo 72 VI Mo 60 V O 372 (ClCH 2 COO) 30 (H 2 O) 72 )] · 250H 2 O · 15ClCH 2 COONa ( II ), in particular, as parts of polymer-contain...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of inorganic chemistry 2011, Vol.56 (2), p.276-281
Main Authors: Ostroushko, A. A., Korotaev, V. Yu, Tonkushina, M. O., Vazhenin, V. A., Artemov, M. Yu, Men’shikov, S. Yu, Kutyashev, I. B.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Infrared radiation
Inorganic Chemistry
Molybdenum
Nuclear magnetic resonance
Physical Methods of Investigation
Polyoxometallates
Raman spectroscopy
Spectra
Spectroscopic analysis
Spectroscopy
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Molybdenum polyoxometallates with the buckyball structure, ((NH 4 ) 42 [Mo 72 VI Mo 60 V O 372 (H 3 CCOO) 30 (H 2 O) 72 ] · 30H 3 CCOONH 4 · 250H 2 O ( I ), (NH 4 ) 42 [Mo 72 VI Mo 60 V O 372 (ClCH 2 COO) 30 (H 2 O) 72 )] · 250H 2 O · 15ClCH 2 COONa ( II ), in particular, as parts of polymer-containing compositions were studied by EPR, NMR, IR, and Raman spectroscopy. The structural and chemical aspects responsible for the formation of the observed spectra were considered.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023611020227