Mechanical and corrosion resistance of a new nanostructured Ti–Zr–Ta–Nb alloy

• Published in: Journal of the mechanical behavior of biomedical materials 2011-10, Vol.4 (7), p.1421-1430
• Main Authors: Raducanu, D., Vasilescu, E., Cojocaru, V.D., Cinca, I., Drob, P., Vasilescu, C., Drob, S.I.
• Format: Article
• Language: English
• Subjects: Accumulative roll bonding (ARB) processing; Alloy development; Alloying elements; Alloys - chemistry; Biomedical materials; Coated Materials, Biocompatible - chemistry; Corrosion; Corrosion resistance; Deformation; Elastoplasticity; Fracture behaviour; Mechanical Phenomena; Nanostructures - chemistry; New Ti–10Zr–5Nb–5Ta alloy; Niobium - chemistry; Strain hardening; Surgical implants; Tantalum - chemistry; Titanium - chemistry; Titanium base alloys; Young’s modulus; Zirconium - chemistry
• ISSN: 1751-6161; 1878-0180
• DOI: 10.1016/j.jmbbm.2011.05.012

In this work, a multi-elementary Ti–10Zr–5Nb–5Ta alloy, with non-toxic alloying elements, was used to develop an accumulative roll bonding, ARB-type procedure in order to improve its structural and mechanical properties. The alloy was obtained by cold crucible semi-levitation melting technique and then was ARB deformed following a special route. After three ARB cycles, the total deformation degree per layer is about 86%; the calculated medium layer thickness is about 13 μm. The ARB processed alloy has a low Young’s modulus of 46 GPa, a value very close to the value of the natural cortical bone (about 20 GPa). Data concerning ultimate tensile strength obtained for ARB processed alloy is rather high, suitable to be used as a material for bone substitute. Hardness of the ARB processed alloy is higher than that of the as-cast alloy, ensuring a better behaviour as a implant material. The tensile curve for the as-cast alloy shows an elastoplastic behaviour with a quite linear elastic behaviour and the tensile curve for the ARB processed alloy is quite similar with a strain-hardening elastoplastic body. Corrosion behaviour of the studied alloy revealed the improvement of the main electrochemical parameters, as a result of the positive influence of ARB processing. Lower corrosion and ion release rates for the ARB processed alloy than for the as-cast alloy, due to the favourable effect of ARB thermo-mechanical processing were obtained. [Display omitted] ► New Ti–10Zr–5Nb–5Ta alloy was processed by an accumulative roll bonding (ARB) method. ► After three ARB cycles, total deformation degree/layer is 86%; medium layer thickness is about 13 μm. ► ARB processed alloy has a low Young’s modulus (46 GPa), very close to the value of the natural cortical bone (30 GPa). ► Ultimate tensile strength for ARB processed alloy is high, suitable for a bone implant. ► Improvement of corrosion resistance as result of ARB processing positive influence was obtained.