Calix[4]arene-supported rare earth octahedra

A series of calix[4]arene-supported Ln(III)(6) clusters have been synthesised under facile bench top conditions. The magnetic and structural properties of these clusters are reported, the latter suggesting that the Ln(III)-calix[4]arene moiety may be used for the construction of other assemblies in...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (10), p.1449-1451
Main Authors: Sanz, Sergio, McIntosh, Ruaraidh D, Beavers, Christine M, Teat, Simon J, Evangelisti, Marco, Brechin, Euan K, Dalgarno, Scott J
Format: Article
Language:English
Subjects:
Analogue
Assemblies
Benches
Calixarenes - chemistry
Clusters
Construction
Crystallography, X-Ray
Lanthanoid Series Elements - chemistry
Models, Molecular
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phenols - chemistry
Rare earth metals
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A series of calix[4]arene-supported Ln(III)(6) clusters have been synthesised under facile bench top conditions. The magnetic and structural properties of these clusters are reported, the latter suggesting that the Ln(III)-calix[4]arene moiety may be used for the construction of other assemblies in a manner akin to that for the Mn(III)-calix[4]arene analogue.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc14603c