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Calix[4]arene-supported rare earth octahedra

A series of calix[4]arene-supported Ln(III)(6) clusters have been synthesised under facile bench top conditions. The magnetic and structural properties of these clusters are reported, the latter suggesting that the Ln(III)-calix[4]arene moiety may be used for the construction of other assemblies in...

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Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (10), p.1449-1451
Main Authors: Sanz, Sergio, McIntosh, Ruaraidh D, Beavers, Christine M, Teat, Simon J, Evangelisti, Marco, Brechin, Euan K, Dalgarno, Scott J
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description A series of calix[4]arene-supported Ln(III)(6) clusters have been synthesised under facile bench top conditions. The magnetic and structural properties of these clusters are reported, the latter suggesting that the Ln(III)-calix[4]arene moiety may be used for the construction of other assemblies in a manner akin to that for the Mn(III)-calix[4]arene analogue.
doi_str_mv 10.1039/c1cc14603c
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ispartof Chemical communications (Cambridge, England), 2012-01, Vol.48 (10), p.1449-1451
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source Royal Society of Chemistry
subjects Analogue
Assemblies
Benches
Calixarenes - chemistry
Clusters
Construction
Crystallography, X-Ray
Lanthanoid Series Elements - chemistry
Models, Molecular
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phenols - chemistry
Rare earth metals
title Calix[4]arene-supported rare earth octahedra
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