Radical polymerization of methyl methacrylate in the presence of benzoyl peroxide, ferrocene and zirconocene dichloride

The controlled radical polymerization of methyl methacrylate initiated by the ferrocene–zirconocene dichloride–benzoyl peroxide system was found to occur as a living radical process with an increased concentration of sindio-triads in the resulting poly(methyl methacrylate).

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Bibliographic Details
Published in:Mendeleev communications 2011-07, Vol.21 (4), p.206-208
Main Authors: Monakov, Yurii B., Islamova, Regina M., Frizen, Anna K., Golovochesova, Olesya I., Nazarova, Svetlana V.
Format: Article
Language:English
Subjects:
Benzoyl peroxide
Dichlorides
Ferrocenes
Peroxides
Polymerization
Polymethyl methacrylates
Radicals
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Description
Summary:The controlled radical polymerization of methyl methacrylate initiated by the ferrocene–zirconocene dichloride–benzoyl peroxide system was found to occur as a living radical process with an increased concentration of sindio-triads in the resulting poly(methyl methacrylate).
ISSN:0959-9436
DOI:10.1016/j.mencom.2011.07.012