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Reactivity ratio of novel acrylic copolymer by NMR spectroscopy
The monomer 4-methylcoumarylacrylate (4-MCA) was synthesized from 7-hydroxy-4-methylcoumarin and characterized by conventional methods. Homo and copolymers of 4-methylcoumarylacrylate and styrene were synthesized with different feed ratios using N,N-dimethylformamide (DMF) as a solvent and 2,2'...
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| Published in: | Colloid and polymer science 2009, Vol.287 (1), p.89-95 |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c402t-16aaa3372085ace4aa5ffe9cecdbcf45e794982c097534c17a167020ebf537d03 |
| container_end_page | 95 |
| container_issue | 1 |
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| container_title | Colloid and polymer science |
| container_volume | 287 |
| creator | Patel, Jaimin R Patel, Kirit H Patel, Rajni M |
| description | The monomer 4-methylcoumarylacrylate (4-MCA) was synthesized from 7-hydroxy-4-methylcoumarin and characterized by conventional methods. Homo and copolymers of 4-methylcoumarylacrylate and styrene were synthesized with different feed ratios using N,N-dimethylformamide (DMF) as a solvent and 2,2'-azobisisobutyronitrile as an initiator at 70°C.The resulting polymers were characterized by infrared spectroscopy. Copolymer compositions were determined by nuclear magnetic resonance spectroscopy. The monomer reactivity ratios were determined by applying the conventional linearization method of Fineman-Ross and Kelen-Tudos. The reactivity ratios values of 4-methylcoumarylacrylate and styrene obtained from F-R plot are 1.36 and 0.62, respectively, and from K-T plot 1.24 and 0.58, respectively. |
| doi_str_mv | 10.1007/s00396-008-1943-6 |
| format | article |
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Homo and copolymers of 4-methylcoumarylacrylate and styrene were synthesized with different feed ratios using N,N-dimethylformamide (DMF) as a solvent and 2,2'-azobisisobutyronitrile as an initiator at 70°C.The resulting polymers were characterized by infrared spectroscopy. Copolymer compositions were determined by nuclear magnetic resonance spectroscopy. The monomer reactivity ratios were determined by applying the conventional linearization method of Fineman-Ross and Kelen-Tudos. The reactivity ratios values of 4-methylcoumarylacrylate and styrene obtained from F-R plot are 1.36 and 0.62, respectively, and from K-T plot 1.24 and 0.58, respectively.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-008-1943-6</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Berlin/Heidelberg : Springer-Verlag</publisher><subject>Applied sciences ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Copolymer Composition ; Copolymerization ; Copolymers ; Exact sciences and technology ; Food Science ; Infrared spectroscopy ; Initiators ; Monomers ; Nanotechnology and Microengineering ; NMR spectroscopy ; Organic polymers ; Physical Chemistry ; Physicochemistry of polymers ; Polymer Sciences ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Reactivity ratio ; Short Communication ; Soft and Granular Matter ; Solvents ; Spectroscopy ; Styrenes</subject><ispartof>Colloid and polymer science, 2009, Vol.287 (1), p.89-95</ispartof><rights>Springer-Verlag 2008</rights><rights>2009 INIST-CNRS</rights><rights>Colloid and Polymer Science is a copyright of Springer, 2009.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c402t-16aaa3372085ace4aa5ffe9cecdbcf45e794982c097534c17a167020ebf537d03</citedby><cites>FETCH-LOGICAL-c402t-16aaa3372085ace4aa5ffe9cecdbcf45e794982c097534c17a167020ebf537d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21030932$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Patel, Jaimin R</creatorcontrib><creatorcontrib>Patel, Kirit H</creatorcontrib><creatorcontrib>Patel, Rajni M</creatorcontrib><title>Reactivity ratio of novel acrylic copolymer by NMR spectroscopy</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>The monomer 4-methylcoumarylacrylate (4-MCA) was synthesized from 7-hydroxy-4-methylcoumarin and characterized by conventional methods. Homo and copolymers of 4-methylcoumarylacrylate and styrene were synthesized with different feed ratios using N,N-dimethylformamide (DMF) as a solvent and 2,2'-azobisisobutyronitrile as an initiator at 70°C.The resulting polymers were characterized by infrared spectroscopy. Copolymer compositions were determined by nuclear magnetic resonance spectroscopy. The monomer reactivity ratios were determined by applying the conventional linearization method of Fineman-Ross and Kelen-Tudos. The reactivity ratios values of 4-methylcoumarylacrylate and styrene obtained from F-R plot are 1.36 and 0.62, respectively, and from K-T plot 1.24 and 0.58, respectively.</description><subject>Applied sciences</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Copolymer Composition</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Infrared spectroscopy</subject><subject>Initiators</subject><subject>Monomers</subject><subject>Nanotechnology and Microengineering</subject><subject>NMR spectroscopy</subject><subject>Organic polymers</subject><subject>Physical Chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Reactivity ratio</subject><subject>Short Communication</subject><subject>Soft and Granular Matter</subject><subject>Solvents</subject><subject>Spectroscopy</subject><subject>Styrenes</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAQx4MouD4-gCcLIp6qk6RJmpPI4gt8gA_wFmZjIpVusyZdod_eLBURD57mML_5z8yPkD0KxxRAnSQArmUJUJdUV7yUa2RCKy5KKrhcJxPgwMsK2Msm2UrpHQAqLeWEnD44tH3z2fRDEbFvQhF80YVP1xZo49A2trBhEdph7mIxG4q724ciLZztY0i5MeyQDY9tcrvfdZs8X5w_Ta_Km_vL6-nZTWnz0r6kEhE5VwxqgdZViMJ7p62zrzPrK-GUrnTNLGgleGWpQioVMHAzL7h6Bb5NjsbcRQwfS5d6M2-SdW2LnQvLZDTVmilRy0we_CHfwzJ2-ThDa8WEZrzmmaIjZfMjKTpvFrGZYxwMBbMyakajJhs1K6NmlXz4nYzJYusjdrZJP4OMZsmas8yxkUu51b25-OuCf8L3xyGPweBbzMHPjwwoByoUY1LyL2WzjgU</recordid><startdate>2009</startdate><enddate>2009</enddate><creator>Patel, Jaimin R</creator><creator>Patel, Kirit H</creator><creator>Patel, Rajni M</creator><general>Berlin/Heidelberg : Springer-Verlag</general><general>Springer-Verlag</general><general>Springer</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>2009</creationdate><title>Reactivity ratio of novel acrylic copolymer by NMR spectroscopy</title><author>Patel, Jaimin R ; Patel, Kirit H ; Patel, Rajni M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c402t-16aaa3372085ace4aa5ffe9cecdbcf45e794982c097534c17a167020ebf537d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Copolymer Composition</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Exact sciences and technology</topic><topic>Food Science</topic><topic>Infrared spectroscopy</topic><topic>Initiators</topic><topic>Monomers</topic><topic>Nanotechnology and Microengineering</topic><topic>NMR spectroscopy</topic><topic>Organic polymers</topic><topic>Physical Chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Reactivity ratio</topic><topic>Short Communication</topic><topic>Soft and Granular Matter</topic><topic>Solvents</topic><topic>Spectroscopy</topic><topic>Styrenes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Patel, Jaimin R</creatorcontrib><creatorcontrib>Patel, Kirit H</creatorcontrib><creatorcontrib>Patel, Rajni M</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Patel, Jaimin R</au><au>Patel, Kirit H</au><au>Patel, Rajni M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactivity ratio of novel acrylic copolymer by NMR spectroscopy</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2009</date><risdate>2009</risdate><volume>287</volume><issue>1</issue><spage>89</spage><epage>95</epage><pages>89-95</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>The monomer 4-methylcoumarylacrylate (4-MCA) was synthesized from 7-hydroxy-4-methylcoumarin and characterized by conventional methods. Homo and copolymers of 4-methylcoumarylacrylate and styrene were synthesized with different feed ratios using N,N-dimethylformamide (DMF) as a solvent and 2,2'-azobisisobutyronitrile as an initiator at 70°C.The resulting polymers were characterized by infrared spectroscopy. Copolymer compositions were determined by nuclear magnetic resonance spectroscopy. The monomer reactivity ratios were determined by applying the conventional linearization method of Fineman-Ross and Kelen-Tudos. The reactivity ratios values of 4-methylcoumarylacrylate and styrene obtained from F-R plot are 1.36 and 0.62, respectively, and from K-T plot 1.24 and 0.58, respectively.</abstract><cop>Berlin/Heidelberg</cop><pub>Berlin/Heidelberg : Springer-Verlag</pub><doi>10.1007/s00396-008-1943-6</doi><tpages>7</tpages></addata></record> |
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| subjects | Applied sciences Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Copolymer Composition Copolymerization Copolymers Exact sciences and technology Food Science Infrared spectroscopy Initiators Monomers Nanotechnology and Microengineering NMR spectroscopy Organic polymers Physical Chemistry Physicochemistry of polymers Polymer Sciences Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Reactivity ratio Short Communication Soft and Granular Matter Solvents Spectroscopy Styrenes |
| title | Reactivity ratio of novel acrylic copolymer by NMR spectroscopy |
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