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Identification of nitro-compounds with LIBS
Laser-induced breakdown spectroscopy (LIBS) is applied to characterize the organic compounds 4-nitroaniline and 4-nitrotoluene by measuring the intensity of atomic lines. The hypothesis of local thermodynamic equilibrium (LTE) is verified by comparing the measured value of electron density in the la...
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Published in: | Applied physics. B, Lasers and optics Lasers and optics, 2008-06, Vol.91 (3-4), p.645-650 |
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container_title | Applied physics. B, Lasers and optics |
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creator | Rai, S. Rai, A.K. Thakur, S.N. |
description | Laser-induced breakdown spectroscopy (LIBS) is applied to characterize the organic compounds 4-nitroaniline and 4-nitrotoluene by measuring the intensity of atomic lines. The hypothesis of local thermodynamic equilibrium (LTE) is verified by comparing the measured value of electron density in the laser-induced plasma with its lower limit, for which LTE holds good. The present study infers that the O/N intensity ratio is a unique parameter to discriminate each nitro-compound from the explosives. |
doi_str_mv | 10.1007/s00340-008-3040-4 |
format | article |
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The hypothesis of local thermodynamic equilibrium (LTE) is verified by comparing the measured value of electron density in the laser-induced plasma with its lower limit, for which LTE holds good. 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subjects | Atomic and molecular physics Biological and medical applications Breakdown Electron density Engineering Exact sciences and technology Explosives Fundamental areas of phenomenology (including applications) Infrared spectra Laser spectroscopy Lasers Local thermodynamic equilibrium Molecular properties and interactions with photons Molecular spectra Optical Devices Optics Organic compounds Photonics Physical Chemistry Physics Physics and Astronomy Physics of gases, plasmas and electric discharges Physics of plasmas and electric discharges Plasma (physics) Plasma production and heating Plasma production and heating by laser beams Quantum Optics Spectroscopy |
title | Identification of nitro-compounds with LIBS |
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