Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

Ruthenium-catalyzed oxidative C–H bond olefination of N-methoxybenzamides using an oxidizing directing group with a broad substrate scope is reported. The reactions of N-methoxybenzamides with acrylates in MeOH and styrene (or norbornadiene) in CF3CH2OH afforded two types of products.

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Bibliographic Details
Published in:Organic letters 2012-02, Vol.14 (3), p.736-739
Main Authors: Li, Bin, Ma, Jianfeng, Wang, Nuancheng, Feng, Huiliang, Xu, Shansheng, Wang, Baiquan
Format: Article
Language:English
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Summary:Ruthenium-catalyzed oxidative C–H bond olefination of N-methoxybenzamides using an oxidizing directing group with a broad substrate scope is reported. The reactions of N-methoxybenzamides with acrylates in MeOH and styrene (or norbornadiene) in CF3CH2OH afforded two types of products.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol2032575