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Spontaneous Emission Control of CdSe/ZnS Nanoparticle Monolayer in Polymer Nanosheet Waveguide Assembled on a One-Dimensional Silver Grating Surface

We present spontaneous emission control of a core–shell CdSe/ZnS nanoparticle array assembled with polymer ultrathin films consisting of polymer nanosheets on a silver grating substrate, which served as a unique and simple photonic cavity. The grating-coupled waveguide modes enabled 103 order lumine...

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Bibliographic Details
Published in:Langmuir 2012-02, Vol.28 (5), p.2313-2317
Main Authors: Mitsuishi, Masaya, Morita, Shimpei, Tawa, Keiko, Nishii, Junji, Miyashita, Tokuji
Format: Article
Language:English
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Summary:We present spontaneous emission control of a core–shell CdSe/ZnS nanoparticle array assembled with polymer ultrathin films consisting of polymer nanosheets on a silver grating substrate, which served as a unique and simple photonic cavity. The grating-coupled waveguide modes enabled 103 order luminescence enhancement and one-fourth spectral narrowing. The light emission from a CdSe/ZnS nanoparticle array can be controlled by tuning the film thickness of hybrid polymer nanoassemblies, which provides multiple emission performance with good tuning ability from red to green at low-power continuous wave laser excitation (∼μW).
ISSN:0743-7463
1520-5827
DOI:10.1021/la2042229