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Mesoporous metal-organic framework materials
Metal-organic frameworks (MOFs) have emerged as a new type of porous materials for diverse applications. Most open MOFs reported to date are microporous (pore sizes
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Published in: | Chemical Society reviews 2012-03, Vol.41 (5), p.1677-1695 |
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Language: | English |
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container_end_page | 1695 |
container_issue | 5 |
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container_title | Chemical Society reviews |
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creator | Xuan, Weimin Zhu, Chengfeng Liu, Yan Cui, Yong |
description | Metal-organic frameworks (MOFs) have emerged as a new type of porous materials for diverse applications. Most open MOFs reported to date are microporous (pore sizes |
doi_str_mv | 10.1039/c1cs15196g |
format | article |
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Most open MOFs reported to date are microporous (pore sizes <2 nm), and only a small fraction of MOFs with ordered mesoscale domains (2-50 nm) is reported. This tutorial review covers recent advances in the field of mesoporous MOFs (mesoMOFs), including their design and synthesis, porosity activation and surface modification, and potential applications in storage and separation, catalysis, drug delivery and imaging. Their specificities are dependent on the pore shape, size, and chemical environments of the cages or channels. The relationship between the structures and functions is discussed. 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title | Mesoporous metal-organic framework materials |
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