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Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates

The two faces of curium: The first curium borate has been prepared showing a complex structure with coordination environments for CmIII that are found in both PuIII and AmIII borates (see picture). Time‐resolved laser‐induced photoluminescence studies as well as X‐ray diffraction experiments show tw...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2012-02, Vol.51 (8), p.1869-1872
Main Authors: Polinski, Matthew J., Wang, Shuao, Alekseev, Evgeny V., Depmeier, Wulf, Liu, Guokui, Haire, Richard G., Albrecht-Schmitt, Thomas E.
Format: Article
Language:English
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Summary:The two faces of curium: The first curium borate has been prepared showing a complex structure with coordination environments for CmIII that are found in both PuIII and AmIII borates (see picture). Time‐resolved laser‐induced photoluminescence studies as well as X‐ray diffraction experiments show two distinct CmIII sites with different coordination environments.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201107956