Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc fi...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (24), p.2973-2975
Main Authors: Wang, Hailong, Wang, Kang, Tao, Jun, Jiang, Jianzhuang
Format: Article
Language:English
Subjects:
Correlation
Direct current
Inference
Magnetization
Molecular structure
Perturbation
Tunneling
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Summary:Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc16543k