Equilibrium and kinetics study on hexavalent chromium adsorption onto diethylene triamine grafted glycidyl methacrylate based copolymers

• Published in: Journal of hazardous materials 2012-03, Vol.209-210, p.99-110
• Main Authors: Maksin, Danijela D., Nastasović, Aleksandra B., Milutinović-Nikolić, Aleksandra D., Suručić, Ljiljana T., Sandić, Zvjezdana P., Hercigonja, Radmila V., Onjia, Antonije E.
• Format: Article
• Language: English
• Subjects: active sites; Adsorption; chromium; Chromium - chemistry; Chromium(VI) sorption; composite polymers; crosslinking; Diethylene triamine; Equilibrium isotherms; Glycidyl methacrylate; Kinetics; mercury; Microscopy, Electron, Scanning; Microscopy, Electron, Transmission; Models, Chemical; Polyamines - chemistry; Polymers - chemistry; scanning electron microscopy; sorption isotherms; Sorption kinetics; spectroscopy; temperature; Thermodynamics; transmission electron microscopy; X-radiation
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2011.12.079

► Methacrylate based copolymers grafted with diethylene triamine as Cr(VI) sorbents. ► Chemisorption and pore diffusion are characteristics of this sorption system. ► Langmuir isotherm provided best fit and maximum adsorption capacity was 143mgg−1. ► Cr(VI) sorption onto amino-functionalized copolymer was endothermic and spontaneous. ► A simple, efficient and cost-effective hexavalent chromium removal method. Two porous and one non-porous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) [abbreviated PGME] were prepared by suspension copolymerization and functionalized with diethylene triamine [abbreviated PGME-deta]. Samples were characterized by elemental analysis, mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy, and transmission electron microscopy. Kinetics of Cr(VI) sorption by PGME-deta were investigated in batch static experiments, in the temperature range 25–70°C. Sorption was rapid, with the uptake capacity higher than 80% after 30min. Sorption behavior and rate-controlling mechanisms were analyzed using five kinetic models (pseudo-first order, pseudo-second order, Elovich, intraparticle diffusion and Bangham model). Kinetic studies showed that Cr(VI) adsorption adhered to the pseudo-second-order model, with definite influence of pore diffusion. Equilibrium data was tested with Langmuir, Freundlich and Tempkin adsorption isotherm models. Langmuir model was the most suitable indicating homogeneous distribution of active sites on PGME-deta and monolayer sorption. The maximum adsorption capacity from the Langmuir model, Qmax, at pH 1.8 and 25°C was 143mgg−1 for PGME2-deta (sample with the highest amino group concentration) while at 70°C Qmax reached the high value of 198mgg−1. Thermodynamic parameters revealed spontaneous and endothermic nature of Cr(VI) adsorption onto PGME-deta.