Organic Complexed Superphosphates (CSP): Physicochemical Characterization and Agronomical Properties

• Published in: Journal of agricultural and food chemistry 2012-02, Vol.60 (8), p.2008-2017
• Main Authors: Erro, Javier, Urrutia, Oscar, Baigorri, Roberto, Aparicio-Tejo, Pedro, Irigoyen, Ignacio, Storino, Francesco, Mandado, Marcos, Yvin, Jean Claude, Garcia-Mina, Jose M
• Format: Article
• Language: English
• Subjects: acid soils; Biological and medical sciences; Cereal and baking product industries; chelating agents; Chelating Agents - chemical synthesis; Chelating Agents - chemistry; Chelating Agents - metabolism; Chemical Phenomena; Diphosphates - chemical synthesis; Diphosphates - chemistry; Diphosphates - metabolism; Fertilizers - analysis; Food industries; Fundamental and applied biological sciences. Psychology; greenhouse soils; humic acids; monocalcium phosphate; nuclear magnetic resonance spectroscopy; phosphorus fertilizers; Structure-Activity Relationship; superphosphate; Triticum - growth & development; Triticum - metabolism; wheat; X-ray diffraction
• ISSN: 0021-8561; 1520-5118
• DOI: 10.1021/jf204821j

A new type of superphosphate (organic complexed superphosphate (CSP)) has been developed by the introduction of organic chelating agents, preferably a humic acid (HA), into the chemical reaction of single superphosphate (SSP) production. This modification yielded a product containing monocalcium phosphate complexed by the chelating organic agent through Ca bridges. Theoretically, the presence of these monocalcium–phosphate–humic complexes (MPHC) inhibits phosphate fixation in soil, thus increasing P fertilizer efficiency. This study investigateed the structural and functional features of CSP fertilizers produced employing diverse HA with different structural features. To this end were used complementary analytical techniques: solid-phase 31P NMR, 13C NMR, laser-confocal microscopy, X-ray diffraction, and molecular modeling. Finally, the agronomical efficiency of four CSP have been compared with that of SSP as P sources for wheat plants grown in both alkaline and acidic soils in greenhouse pot trials under controlled conditions. The results obtained from the diverse analytical studies showed the formation of MPHC in CSP. Plant–soil studies showed that CSP products were more efficient than SSP in providing available phosphate for wheat plants cultivated in various soils with different physicochemical features. This fact is probably associated with the ability of CSP complexes to inhibit phosphate fixation in soil.