Photopolymerization of Bis(4-methacryloylmethylphenyl)sulfide and Bis(4-methacryloylmethylphenyl)sulfone with Vinyl Monomers and Properties of the Prepared Copolymers

The reaction of photopolymerization of bis(4-methacryloylmethylphenyl)sulfide (BMcMPhS) and bis(4-methacryloylmethylphenyl)sulfone (BMcMPhSu) with the typical vinyl monomers: methyl methacrylate (MMA) and styrene (St) in the presence of the two photoinitiators: Irgacure 651 and Darocur 1173 are pres...

Full description

Saved in:
Bibliographic Details
Published in:Polymers & polymer composites 2011-09, Vol.19 (7), p.587-592
Main Authors: RUDZ, Wiestaw, GAWDZIK, Barbara
Format: Article
Language:English
Subjects:
Applied sciences
Catalytic polymerization
Copolymers
Elongation
Exact sciences and technology
Gelation
Hardness
Mechanical properties
Monomers
Photoinitiators
Physicochemistry of polymers
Polymerization
Polymers and radiations
Polymethyl methacrylates
Studies
Tensile strength
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c336t-ceaeb06599c508fb3f80f091ed41b980b858e042989a259b6cc6534c8a18ffa3
cites cdi_FETCH-LOGICAL-c336t-ceaeb06599c508fb3f80f091ed41b980b858e042989a259b6cc6534c8a18ffa3
container_end_page 592
container_issue 7
container_start_page 587
container_title Polymers & polymer composites
container_volume 19
creator RUDZ, Wiestaw
GAWDZIK, Barbara
description The reaction of photopolymerization of bis(4-methacryloylmethylphenyl)sulfide (BMcMPhS) and bis(4-methacryloylmethylphenyl)sulfone (BMcMPhSu) with the typical vinyl monomers: methyl methacrylate (MMA) and styrene (St) in the presence of the two photoinitiators: Irgacure 651 and Darocur 1173 are presented. The influence of percentage concentration of BMcMPhS and BMcMPhSu on the gelation times of the prepared copolymers was studied. The effect of the used photoinitiator concentrations on gelation times was also investigated. For the chosen copolymers, mechanical properties including tensile strength, elongation at break, Young modulus, Brinell's and Shore's hardness were determined. The results showed that copolymers with MMA had shorter gelation times than those with St. Gelation times were shorter when Darocur 1173 was used as a photoinitiator. An increase of Darocur 1173 concentration caused a decrease of gelation times, whereas in the case of Irgacure 651 the opposite relation was observed.
doi_str_mv 10.1177/096739111101900709
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_926282146</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>926282146</sourcerecordid><originalsourceid>FETCH-LOGICAL-c336t-ceaeb06599c508fb3f80f091ed41b980b858e042989a259b6cc6534c8a18ffa3</originalsourceid><addsrcrecordid>eNqNkcFO3DAQhq2qSN0ufYGeokpV6SEwdhLHPsKKUiQQe0C9Ro53rBh542BnhcID8Zw4XcqBXpjLjH59__wjDSFfKRxTWtcnIHldSJoKqASoQX4gC1rWImdJ_kgWM5DPxCfyOcY7AEY5rxbkad350Q_eTVsM9lGN1veZN9mZjUdlvsWxUzpMzk9unic3dNhP7mfcOWM3mKl-8x7U95g92LHL_tgkZde-9yku_rWvgx8wjBbjnDt2mBQcVMBNtvp3WDwkB0a5iF9e-pLc_jq_Xf3Or24uLlenV7kuCj7mGhW2wCspdQXCtIURYEBS3JS0lQJaUQmEkkkhFatky7XmVVFqoagwRhVL8mO_dgj-fodxbLY2anRO9eh3sZGMM8FoyRP57Q1553ehT7c1ok6QAMYSxPaQDj7GgKYZgt2qMDUUmvlvzf9_S6bvL5tV1MqZoHpt46uTlQVQLuriGYcYnDk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>876288022</pqid></control><display><type>article</type><title>Photopolymerization of Bis(4-methacryloylmethylphenyl)sulfide and Bis(4-methacryloylmethylphenyl)sulfone with Vinyl Monomers and Properties of the Prepared Copolymers</title><source>Sage Journals GOLD Open Access 2024</source><creator>RUDZ, Wiestaw ; GAWDZIK, Barbara</creator><creatorcontrib>RUDZ, Wiestaw ; GAWDZIK, Barbara</creatorcontrib><description>The reaction of photopolymerization of bis(4-methacryloylmethylphenyl)sulfide (BMcMPhS) and bis(4-methacryloylmethylphenyl)sulfone (BMcMPhSu) with the typical vinyl monomers: methyl methacrylate (MMA) and styrene (St) in the presence of the two photoinitiators: Irgacure 651 and Darocur 1173 are presented. The influence of percentage concentration of BMcMPhS and BMcMPhSu on the gelation times of the prepared copolymers was studied. The effect of the used photoinitiator concentrations on gelation times was also investigated. For the chosen copolymers, mechanical properties including tensile strength, elongation at break, Young modulus, Brinell's and Shore's hardness were determined. The results showed that copolymers with MMA had shorter gelation times than those with St. Gelation times were shorter when Darocur 1173 was used as a photoinitiator. An increase of Darocur 1173 concentration caused a decrease of gelation times, whereas in the case of Irgacure 651 the opposite relation was observed.</description><identifier>ISSN: 0967-3911</identifier><identifier>EISSN: 1478-2391</identifier><identifier>DOI: 10.1177/096739111101900709</identifier><language>eng</language><publisher>Shrewsbury: Rapra</publisher><subject>Applied sciences ; Catalytic polymerization ; Copolymers ; Elongation ; Exact sciences and technology ; Gelation ; Hardness ; Mechanical properties ; Monomers ; Photoinitiators ; Physicochemistry of polymers ; Polymerization ; Polymers and radiations ; Polymethyl methacrylates ; Studies ; Tensile strength</subject><ispartof>Polymers &amp; polymer composites, 2011-09, Vol.19 (7), p.587-592</ispartof><rights>2015 INIST-CNRS</rights><rights>Copyright Smithers Rapra Technology Limited 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c336t-ceaeb06599c508fb3f80f091ed41b980b858e042989a259b6cc6534c8a18ffa3</citedby><cites>FETCH-LOGICAL-c336t-ceaeb06599c508fb3f80f091ed41b980b858e042989a259b6cc6534c8a18ffa3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=24301687$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>RUDZ, Wiestaw</creatorcontrib><creatorcontrib>GAWDZIK, Barbara</creatorcontrib><title>Photopolymerization of Bis(4-methacryloylmethylphenyl)sulfide and Bis(4-methacryloylmethylphenyl)sulfone with Vinyl Monomers and Properties of the Prepared Copolymers</title><title>Polymers &amp; polymer composites</title><description>The reaction of photopolymerization of bis(4-methacryloylmethylphenyl)sulfide (BMcMPhS) and bis(4-methacryloylmethylphenyl)sulfone (BMcMPhSu) with the typical vinyl monomers: methyl methacrylate (MMA) and styrene (St) in the presence of the two photoinitiators: Irgacure 651 and Darocur 1173 are presented. The influence of percentage concentration of BMcMPhS and BMcMPhSu on the gelation times of the prepared copolymers was studied. The effect of the used photoinitiator concentrations on gelation times was also investigated. For the chosen copolymers, mechanical properties including tensile strength, elongation at break, Young modulus, Brinell's and Shore's hardness were determined. The results showed that copolymers with MMA had shorter gelation times than those with St. Gelation times were shorter when Darocur 1173 was used as a photoinitiator. An increase of Darocur 1173 concentration caused a decrease of gelation times, whereas in the case of Irgacure 651 the opposite relation was observed.</description><subject>Applied sciences</subject><subject>Catalytic polymerization</subject><subject>Copolymers</subject><subject>Elongation</subject><subject>Exact sciences and technology</subject><subject>Gelation</subject><subject>Hardness</subject><subject>Mechanical properties</subject><subject>Monomers</subject><subject>Photoinitiators</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers and radiations</subject><subject>Polymethyl methacrylates</subject><subject>Studies</subject><subject>Tensile strength</subject><issn>0967-3911</issn><issn>1478-2391</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqNkcFO3DAQhq2qSN0ufYGeokpV6SEwdhLHPsKKUiQQe0C9Ro53rBh542BnhcID8Zw4XcqBXpjLjH59__wjDSFfKRxTWtcnIHldSJoKqASoQX4gC1rWImdJ_kgWM5DPxCfyOcY7AEY5rxbkad350Q_eTVsM9lGN1veZN9mZjUdlvsWxUzpMzk9unic3dNhP7mfcOWM3mKl-8x7U95g92LHL_tgkZde-9yku_rWvgx8wjBbjnDt2mBQcVMBNtvp3WDwkB0a5iF9e-pLc_jq_Xf3Or24uLlenV7kuCj7mGhW2wCspdQXCtIURYEBS3JS0lQJaUQmEkkkhFatky7XmVVFqoagwRhVL8mO_dgj-fodxbLY2anRO9eh3sZGMM8FoyRP57Q1553ehT7c1ok6QAMYSxPaQDj7GgKYZgt2qMDUUmvlvzf9_S6bvL5tV1MqZoHpt46uTlQVQLuriGYcYnDk</recordid><startdate>20110901</startdate><enddate>20110901</enddate><creator>RUDZ, Wiestaw</creator><creator>GAWDZIK, Barbara</creator><general>Rapra</general><general>Sage Publications Ltd</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>EHMNL</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2O</scope><scope>M2P</scope><scope>MBDVC</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope></search><sort><creationdate>20110901</creationdate><title>Photopolymerization of Bis(4-methacryloylmethylphenyl)sulfide and Bis(4-methacryloylmethylphenyl)sulfone with Vinyl Monomers and Properties of the Prepared Copolymers</title><author>RUDZ, Wiestaw ; GAWDZIK, Barbara</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c336t-ceaeb06599c508fb3f80f091ed41b980b858e042989a259b6cc6534c8a18ffa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Catalytic polymerization</topic><topic>Copolymers</topic><topic>Elongation</topic><topic>Exact sciences and technology</topic><topic>Gelation</topic><topic>Hardness</topic><topic>Mechanical properties</topic><topic>Monomers</topic><topic>Photoinitiators</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers and radiations</topic><topic>Polymethyl methacrylates</topic><topic>Studies</topic><topic>Tensile strength</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>RUDZ, Wiestaw</creatorcontrib><creatorcontrib>GAWDZIK, Barbara</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>UK &amp; Ireland Database</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Proquest Research Library</collection><collection>Science Database</collection><collection>Research Library (Corporate)</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><jtitle>Polymers &amp; polymer composites</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>RUDZ, Wiestaw</au><au>GAWDZIK, Barbara</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photopolymerization of Bis(4-methacryloylmethylphenyl)sulfide and Bis(4-methacryloylmethylphenyl)sulfone with Vinyl Monomers and Properties of the Prepared Copolymers</atitle><jtitle>Polymers &amp; polymer composites</jtitle><date>2011-09-01</date><risdate>2011</risdate><volume>19</volume><issue>7</issue><spage>587</spage><epage>592</epage><pages>587-592</pages><issn>0967-3911</issn><eissn>1478-2391</eissn><abstract>The reaction of photopolymerization of bis(4-methacryloylmethylphenyl)sulfide (BMcMPhS) and bis(4-methacryloylmethylphenyl)sulfone (BMcMPhSu) with the typical vinyl monomers: methyl methacrylate (MMA) and styrene (St) in the presence of the two photoinitiators: Irgacure 651 and Darocur 1173 are presented. The influence of percentage concentration of BMcMPhS and BMcMPhSu on the gelation times of the prepared copolymers was studied. The effect of the used photoinitiator concentrations on gelation times was also investigated. For the chosen copolymers, mechanical properties including tensile strength, elongation at break, Young modulus, Brinell's and Shore's hardness were determined. The results showed that copolymers with MMA had shorter gelation times than those with St. Gelation times were shorter when Darocur 1173 was used as a photoinitiator. An increase of Darocur 1173 concentration caused a decrease of gelation times, whereas in the case of Irgacure 651 the opposite relation was observed.</abstract><cop>Shrewsbury</cop><pub>Rapra</pub><doi>10.1177/096739111101900709</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0967-3911
ispartof Polymers & polymer composites, 2011-09, Vol.19 (7), p.587-592
issn 0967-3911
1478-2391
language eng
recordid cdi_proquest_miscellaneous_926282146
source Sage Journals GOLD Open Access 2024
subjects Applied sciences
Catalytic polymerization
Copolymers
Elongation
Exact sciences and technology
Gelation
Hardness
Mechanical properties
Monomers
Photoinitiators
Physicochemistry of polymers
Polymerization
Polymers and radiations
Polymethyl methacrylates
Studies
Tensile strength
title Photopolymerization of Bis(4-methacryloylmethylphenyl)sulfide and Bis(4-methacryloylmethylphenyl)sulfone with Vinyl Monomers and Properties of the Prepared Copolymers
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T21%3A35%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photopolymerization%20of%20Bis(4-methacryloylmethylphenyl)sulfide%20and%20Bis(4-methacryloylmethylphenyl)sulfone%20with%20Vinyl%20Monomers%20and%20Properties%20of%20the%20Prepared%20Copolymers&rft.jtitle=Polymers%20&%20polymer%20composites&rft.au=RUDZ,%20Wiestaw&rft.date=2011-09-01&rft.volume=19&rft.issue=7&rft.spage=587&rft.epage=592&rft.pages=587-592&rft.issn=0967-3911&rft.eissn=1478-2391&rft_id=info:doi/10.1177/096739111101900709&rft_dat=%3Cproquest_cross%3E926282146%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c336t-ceaeb06599c508fb3f80f091ed41b980b858e042989a259b6cc6534c8a18ffa3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=876288022&rft_id=info:pmid/&rfr_iscdi=true