Improved Hydrogen Release from Ammonia–Borane with ZIF-8

The promotion for hydrogen release from ammonia–borane (AB) was observed in the presence of ZIF-8. Even at concentrations of ZIF-8 as low as 0.25 mol %, a reduction of the onset temperature for dehydrogenation accompanies an increase in both the rate and amount of hydrogen released from AB.

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Bibliographic Details
Published in:Inorganic chemistry 2012-03, Vol.51 (5), p.2728-2730
Main Authors: Zhong, Rui-Qin, Zou, Ru-Qiang, Nakagawa, Tessui, Janicke, Michael, Semelsberger, Troy A, Burrell, Anthony K, Del Sesto, Rico E
Format: Article
Language:English
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Summary:The promotion for hydrogen release from ammonia–borane (AB) was observed in the presence of ZIF-8. Even at concentrations of ZIF-8 as low as 0.25 mol %, a reduction of the onset temperature for dehydrogenation accompanies an increase in both the rate and amount of hydrogen released from AB.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic202562b