Electrochemical study of the metal extractant 4-chloro-N-8-quinolinylbenzenesulfonamide

The electrochemical behaviour of the reagent 4-chloro-N-8-quinolinylbenzenesulfonamide has been studied by sampled direct current and differential pulse polarography as well as by cyclic voltamperometry techniques. Three reduction waves are obtained and the reversibility and nature of the electrodic...

Full description

Saved in:
Bibliographic Details
Published in:European journal of chemistry 2011-12, Vol.2 (4), p.441-447
Main Authors: Huebra, Marta, Elizalde, Maria Puy
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c810-3a67755d75898090cd7941aac0e15a0383f79f9ae0f50bb3d5afe52a95648ac43
container_end_page 447
container_issue 4
container_start_page 441
container_title European journal of chemistry
container_volume 2
creator Huebra, Marta
Elizalde, Maria Puy
description The electrochemical behaviour of the reagent 4-chloro-N-8-quinolinylbenzenesulfonamide has been studied by sampled direct current and differential pulse polarography as well as by cyclic voltamperometry techniques. Three reduction waves are obtained and the reversibility and nature of the electrodic processes are discussed. The first and third reduction waves have been explained through chemical reactions and adsorption processes involving the interaction with mercury as electrodic material, whereas the second wave is attributed to the reduction process of the reagent itself. Acidity constant values of the compound in 0.1 M KCl / 25 % methanol medium through polarographic measurements are also given. The influence of the addition of copper to the hydroalcoholic solution in the electrochemical reduction of the reagent is also described.
doi_str_mv 10.5155/eurjchem.2.4.441-447.417
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_926886090</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>926886090</sourcerecordid><originalsourceid>FETCH-LOGICAL-c810-3a67755d75898090cd7941aac0e15a0383f79f9ae0f50bb3d5afe52a95648ac43</originalsourceid><addsrcrecordid>eNo9kE1rAyEQhqW00JDmP-ytJ7e6atRjCekHhPYS6FGMO5IN7pqoC01_fTf0Y2CYl-HlOTwIVZTUggrxAGM6uD30dVPzmnOKOZc1p_IKzRoqGG4aIa__M9e3aJHzgUzDGJVSztDHOoArKV4onbOhymVsz1X0VdlD1UOZXvBZknXFDqXi2O1DTBG_YYVPYzfE0A3nsIPhCwbIY_BxsH3Xwh268TZkWPzeOdo-rberF7x5f35dPW6wU5RgZpdSCtFKobQimrhWak6tdQSosIQp5qX22gLxgux2rBXWg2isFkuurONsju5_sMcUTyPkYvouOwjBDhDHbHSzVGo5kaem-mm6FHNO4M0xdb1NZ0OJucg0fzJNY7iZZE4rzSSTfQPABGvo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>926886090</pqid></control><display><type>article</type><title>Electrochemical study of the metal extractant 4-chloro-N-8-quinolinylbenzenesulfonamide</title><source>Free Full-Text Journals in Chemistry</source><creator>Huebra, Marta ; Elizalde, Maria Puy</creator><creatorcontrib>Huebra, Marta ; Elizalde, Maria Puy</creatorcontrib><description>The electrochemical behaviour of the reagent 4-chloro-N-8-quinolinylbenzenesulfonamide has been studied by sampled direct current and differential pulse polarography as well as by cyclic voltamperometry techniques. Three reduction waves are obtained and the reversibility and nature of the electrodic processes are discussed. The first and third reduction waves have been explained through chemical reactions and adsorption processes involving the interaction with mercury as electrodic material, whereas the second wave is attributed to the reduction process of the reagent itself. Acidity constant values of the compound in 0.1 M KCl / 25 % methanol medium through polarographic measurements are also given. The influence of the addition of copper to the hydroalcoholic solution in the electrochemical reduction of the reagent is also described.</description><identifier>ISSN: 2153-2249</identifier><identifier>EISSN: 2153-2257</identifier><identifier>DOI: 10.5155/eurjchem.2.4.441-447.417</identifier><language>eng</language><ispartof>European journal of chemistry, 2011-12, Vol.2 (4), p.441-447</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c810-3a67755d75898090cd7941aac0e15a0383f79f9ae0f50bb3d5afe52a95648ac43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Huebra, Marta</creatorcontrib><creatorcontrib>Elizalde, Maria Puy</creatorcontrib><title>Electrochemical study of the metal extractant 4-chloro-N-8-quinolinylbenzenesulfonamide</title><title>European journal of chemistry</title><description>The electrochemical behaviour of the reagent 4-chloro-N-8-quinolinylbenzenesulfonamide has been studied by sampled direct current and differential pulse polarography as well as by cyclic voltamperometry techniques. Three reduction waves are obtained and the reversibility and nature of the electrodic processes are discussed. The first and third reduction waves have been explained through chemical reactions and adsorption processes involving the interaction with mercury as electrodic material, whereas the second wave is attributed to the reduction process of the reagent itself. Acidity constant values of the compound in 0.1 M KCl / 25 % methanol medium through polarographic measurements are also given. The influence of the addition of copper to the hydroalcoholic solution in the electrochemical reduction of the reagent is also described.</description><issn>2153-2249</issn><issn>2153-2257</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNo9kE1rAyEQhqW00JDmP-ytJ7e6atRjCekHhPYS6FGMO5IN7pqoC01_fTf0Y2CYl-HlOTwIVZTUggrxAGM6uD30dVPzmnOKOZc1p_IKzRoqGG4aIa__M9e3aJHzgUzDGJVSztDHOoArKV4onbOhymVsz1X0VdlD1UOZXvBZknXFDqXi2O1DTBG_YYVPYzfE0A3nsIPhCwbIY_BxsH3Xwh268TZkWPzeOdo-rberF7x5f35dPW6wU5RgZpdSCtFKobQimrhWak6tdQSosIQp5qX22gLxgux2rBXWg2isFkuurONsju5_sMcUTyPkYvouOwjBDhDHbHSzVGo5kaem-mm6FHNO4M0xdb1NZ0OJucg0fzJNY7iZZE4rzSSTfQPABGvo</recordid><startdate>20111231</startdate><enddate>20111231</enddate><creator>Huebra, Marta</creator><creator>Elizalde, Maria Puy</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope></search><sort><creationdate>20111231</creationdate><title>Electrochemical study of the metal extractant 4-chloro-N-8-quinolinylbenzenesulfonamide</title><author>Huebra, Marta ; Elizalde, Maria Puy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c810-3a67755d75898090cd7941aac0e15a0383f79f9ae0f50bb3d5afe52a95648ac43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huebra, Marta</creatorcontrib><creatorcontrib>Elizalde, Maria Puy</creatorcontrib><collection>CrossRef</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science &amp; Fisheries Abstracts (ASFA) 3: Aquatic Pollution &amp; Environmental Quality</collection><collection>Aquatic Science &amp; Fisheries Abstracts (ASFA) Professional</collection><jtitle>European journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huebra, Marta</au><au>Elizalde, Maria Puy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical study of the metal extractant 4-chloro-N-8-quinolinylbenzenesulfonamide</atitle><jtitle>European journal of chemistry</jtitle><date>2011-12-31</date><risdate>2011</risdate><volume>2</volume><issue>4</issue><spage>441</spage><epage>447</epage><pages>441-447</pages><issn>2153-2249</issn><eissn>2153-2257</eissn><abstract>The electrochemical behaviour of the reagent 4-chloro-N-8-quinolinylbenzenesulfonamide has been studied by sampled direct current and differential pulse polarography as well as by cyclic voltamperometry techniques. Three reduction waves are obtained and the reversibility and nature of the electrodic processes are discussed. The first and third reduction waves have been explained through chemical reactions and adsorption processes involving the interaction with mercury as electrodic material, whereas the second wave is attributed to the reduction process of the reagent itself. Acidity constant values of the compound in 0.1 M KCl / 25 % methanol medium through polarographic measurements are also given. The influence of the addition of copper to the hydroalcoholic solution in the electrochemical reduction of the reagent is also described.</abstract><doi>10.5155/eurjchem.2.4.441-447.417</doi><tpages>7</tpages></addata></record>
fulltext fulltext
identifier ISSN: 2153-2249
ispartof European journal of chemistry, 2011-12, Vol.2 (4), p.441-447
issn 2153-2249
2153-2257
language eng
recordid cdi_proquest_miscellaneous_926886090
source Free Full-Text Journals in Chemistry
title Electrochemical study of the metal extractant 4-chloro-N-8-quinolinylbenzenesulfonamide
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T14%3A47%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrochemical%20study%20of%20the%20metal%20extractant%204-chloro-N-8-quinolinylbenzenesulfonamide&rft.jtitle=European%20journal%20of%20chemistry&rft.au=Huebra,%20Marta&rft.date=2011-12-31&rft.volume=2&rft.issue=4&rft.spage=441&rft.epage=447&rft.pages=441-447&rft.issn=2153-2249&rft.eissn=2153-2257&rft_id=info:doi/10.5155/eurjchem.2.4.441-447.417&rft_dat=%3Cproquest_cross%3E926886090%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c810-3a67755d75898090cd7941aac0e15a0383f79f9ae0f50bb3d5afe52a95648ac43%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=926886090&rft_id=info:pmid/&rfr_iscdi=true