The generation of hydrogen peroxide in the processes of oxidation of aliphatic alcohols in the UV/H sub(2)O sub(2) system

The article has studied the impact of various physicochemical factors (the concentration of H sub(2)O sub(2): alcohol ratio, the presence of oxygen, of Fe(III) ions, etc.) on the consumption and buildup of H sub(2)O sub(2) in oxidation of aliphatic alcohols in aqueous solutions under the effect of U...

Full description

Saved in:
Bibliographic Details
Published in:Journal of water chemistry and technology 2011-10, Vol.33 (5), p.273-280
Main Authors: Nosonovich, A A, Soboleva, N M, Goncharuk, V V
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The article has studied the impact of various physicochemical factors (the concentration of H sub(2)O sub(2): alcohol ratio, the presence of oxygen, of Fe(III) ions, etc.) on the consumption and buildup of H sub(2)O sub(2) in oxidation of aliphatic alcohols in aqueous solutions under the effect of UV light (200-360 nm). Based on the obtained data the kinetic model of generating H sub(2)O sub(2) has been proposed in the processes being considered.
ISSN:1063-455X
1934-936X
DOI:10.3103/S1063455X11050018