Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex

Living radical polymerization (LRP) of organic and water soluble acrylates and acrylamides was mediated by a versatile cobalt porphyrin complex (TMP-OH)Co. The capability of this cobalt complex to mediate LRP in both polar and non-polar media permits the direct synthesis of useful and previously dif...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-04, Vol.48 (29), p.3506-3508
Main Authors: Zhao, Yaguang, Dong, Huilong, Li, Youyong, Fu, Xuefeng
Format: Article
Language:English
Subjects:
Acrylamide
Acrylates
Block copolymers
Cobalt
Polymerization
Porphyrins
Radicals
Synthesis
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Summary:Living radical polymerization (LRP) of organic and water soluble acrylates and acrylamides was mediated by a versatile cobalt porphyrin complex (TMP-OH)Co. The capability of this cobalt complex to mediate LRP in both polar and non-polar media permits the direct synthesis of useful and previously difficult to prepare functional block copolymers.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc00114d