Thermal decomposition of new ruthenium(II) complexes containing N-alkylphenothiazines

Thermal decomposition of chlorpromazine hydrochloride (CP·HCl), trifluoperazine dihydrochloride (TF·2HCl) and thioridazine hydrochloride (TR·HCl), and the ruthenium complexes with dimethyl sulfoxide (dmso) of composition [RuCl 2 (dmso) 4 ] and L[RuCl 3 (dmso) 3 ]· x EtOH, L = CP·HCl, TF·2HCl or TR·H...

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Bibliographic Details
Published in:Journal of thermal analysis and calorimetry 2011-07, Vol.105 (1), p.27-32
Main Authors: Holló, Berta, Krstić, Milena, Sovilj, Sofija P., Pokol, György, Szécsényi, Katalin Mészáros
Format: Article
Language:English
Subjects:
Analysis
Analytical Chemistry
Chemistry
Chemistry and Materials Science
Chlorpromazine
Coordination compounds
Decomposition
Dimethyl sulfoxide
Evaporation
Exact sciences and technology
Hydrochlorides
Inorganic Chemistry
Inorganic chemistry and origins of life
Measurement Science and Instrumentation
Physical Chemistry
Polymer Sciences
Preparations and properties
Ruthenium
Sulfides
Thermal decomposition
Toy industry
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Summary:Thermal decomposition of chlorpromazine hydrochloride (CP·HCl), trifluoperazine dihydrochloride (TF·2HCl) and thioridazine hydrochloride (TR·HCl), and the ruthenium complexes with dimethyl sulfoxide (dmso) of composition [RuCl 2 (dmso) 4 ] and L[RuCl 3 (dmso) 3 ]· x EtOH, L = CP·HCl, TF·2HCl or TR·HCl is described. The phenothiazines are stable to temperature range of 200–280 °C with an increasing stability order of TF·2HCl 
ISSN:1388-6150
1588-2926
1572-8943
DOI:10.1007/s10973-011-1455-3