Unexpected and selective formation of an (e,e,e,e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D2h-hexakis-[60]fullerene adduct

An (e,e,e,e)-tetrakis-adduct of C60 fullerene with two pyridylpyrrolidino addends (trans-1 position relative to each other) and two (ethoxycarbonyl)methano addends (trans-1 position relative to each to other) compound 4, was obtained selectively by controlled potential electrolysis of the D2h-hexaki...

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Bibliographic Details
Published in:Journal of materials chemistry 2011-02, Vol.21 (5), p.1362-1364
Main Authors: Ortiz, Angy L, Echegoyen, Luis
Format: Article
Language:English
Subjects:
Adducts
Buckminsterfullerene
Derivatives
Electrolysis
Fullerenes
Materials selection
Online Access:Get full text
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Summary:An (e,e,e,e)-tetrakis-adduct of C60 fullerene with two pyridylpyrrolidino addends (trans-1 position relative to each other) and two (ethoxycarbonyl)methano addends (trans-1 position relative to each to other) compound 4, was obtained selectively by controlled potential electrolysis of the D2h-hexakis-adduct 3.
ISSN:0959-9428
DOI:10.1039/C0JM00754D