Self-assembly of highly crystalline two-dimensional MOF sheets on liquid surfaces

The formation process of the highly crystalline MOF nanosheet, NAFS-1 at the liquid surface was studied by UV-visible spectroscopy and synchrotron grazing incidence X-ray diffraction - self-assembly of the molecular building metalloporphyrin units and the metal ion joints occurs through a coordinati...

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Bibliographic Details
Published in:CrystEngComm 2011-01, Vol.13 (18), p.5538-5541
Main Authors: Makiura, Rie, Tsuchiyama, Kohei, Sakata, Osami
Format: Article
Language:English
Subjects:
Crystal structure
Liquid surfaces
Liquids
Nanocomposites
Nanomaterials
Nanostructure
Self assembly
Synchrotrons
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Summary:The formation process of the highly crystalline MOF nanosheet, NAFS-1 at the liquid surface was studied by UV-visible spectroscopy and synchrotron grazing incidence X-ray diffraction - self-assembly of the molecular building metalloporphyrin units and the metal ion joints occurs through a coordination reaction at the air/liquid interface without the necessity of pressing the surface.
ISSN:1466-8033
1466-8033
DOI:10.1039/c1ce05684k